Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 38AP
Interpretation Introduction

Interpretation: All the structural formulas of compound with molecular formula C4H11N needs to be determined if no H atom is directly attached to the N atom.

Concept Introduction: For a molecule, all the structural formulas have same molecular formula but the arrangement of atoms in the molecule is different.

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22.16 The following groups are ortho-para directors. (a) -C=CH₂ H (d) -Br (b) -NH2 (c) -OCHS Draw a contributing structure for the resonance-stabilized cation formed during elec- trophilic aromatic substitution that shows the role of each group in stabilizing the intermediate by further delocalizing its positive charge. 22.17 Predict the major product or products from treatment of each compound with Cl₁/FeCl₂- OH (b) NO2 CHO 22.18 How do you account for the fact that phenyl acetate is less reactive toward electro- philic aromatic substitution than anisole? Phenyl acetate Anisole CH (d)
Show how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.
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