Organic And Biological Chemistry
7th Edition
ISBN: 9781305638686
Author: H. Stephen Stoker
Publisher: Brooks Cole
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Question
Chapter 6.13, Problem 1QQ
Interpretation Introduction
Interpretation:
IUPAC name of the given compound has to be chosen from the given options.
Concept Introduction:
Amides are derivatives of
IUPAC rules for naming an amide:
- The end in name of the carboxylic acid is changed from “-ic acid” or “-oic acid” to “-amide”.
- The groups attached to the nitrogen are appended to front of base name by using N-prefix as locator.
For amides, IUPAC name and common names are the named using the same rules.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 6 Solutions
Organic And Biological Chemistry
Ch. 6.1 - Prob. 1QQCh. 6.1 - Prob. 2QQCh. 6.2 - Prob. 1QQCh. 6.2 - Prob. 2QQCh. 6.2 - Prob. 3QQCh. 6.2 - Prob. 4QQCh. 6.3 - Prob. 1QQCh. 6.3 - Prob. 2QQCh. 6.3 - Prob. 3QQCh. 6.3 - Prob. 4QQ
Ch. 6.4 - Prob. 1QQCh. 6.4 - Prob. 2QQCh. 6.5 - Prob. 1QQCh. 6.5 - Prob. 2QQCh. 6.5 - Prob. 3QQCh. 6.6 - Prob. 1QQCh. 6.6 - Prob. 2QQCh. 6.6 - Prob. 3QQCh. 6.7 - Prob. 1QQCh. 6.7 - Prob. 2QQCh. 6.7 - Prob. 3QQCh. 6.8 - Prob. 1QQCh. 6.8 - Prob. 2QQCh. 6.8 - Prob. 3QQCh. 6.8 - Prob. 4QQCh. 6.9 - Prob. 1QQCh. 6.9 - Prob. 2QQCh. 6.10 - Prob. 1QQCh. 6.10 - Prob. 2QQCh. 6.10 - Prob. 3QQCh. 6.10 - Prob. 4QQCh. 6.11 - Prob. 1QQCh. 6.11 - Prob. 2QQCh. 6.11 - Prob. 3QQCh. 6.12 - Prob. 1QQCh. 6.12 - Prob. 2QQCh. 6.12 - Prob. 3QQCh. 6.12 - Prob. 4QQCh. 6.13 - Prob. 1QQCh. 6.13 - Prob. 2QQCh. 6.13 - Prob. 3QQCh. 6.13 - Prob. 4QQCh. 6.14 - Prob. 1QQCh. 6.14 - Prob. 2QQCh. 6.14 - Prob. 3QQCh. 6.15 - Prob. 1QQCh. 6.15 - Prob. 2QQCh. 6.16 - Prob. 1QQCh. 6.16 - Prob. 2QQCh. 6.16 - Prob. 3QQCh. 6.17 - Prob. 1QQCh. 6.17 - Prob. 2QQCh. 6.17 - Prob. 3QQCh. 6.18 - Prob. 1QQCh. 6.18 - Prob. 2QQCh. 6.18 - Prob. 3QQCh. 6.19 - Prob. 1QQCh. 6.19 - Prob. 2QQCh. 6.19 - Prob. 3QQCh. 6.19 - Prob. 4QQCh. 6 - Prob. 6.1EPCh. 6 - Prob. 6.2EPCh. 6 - Prob. 6.3EPCh. 6 - Prob. 6.4EPCh. 6 - Prob. 6.5EPCh. 6 - Prob. 6.6EPCh. 6 - Prob. 6.7EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Indicate whether each of the compounds in Problem...Ch. 6 - Prob. 6.10EPCh. 6 - Prob. 6.11EPCh. 6 - Prob. 6.12EPCh. 6 - Prob. 6.13EPCh. 6 - Prob. 6.14EPCh. 6 - Prob. 6.15EPCh. 6 - Prob. 6.16EPCh. 6 - Prob. 6.17EPCh. 6 - Assign an IUPAC name to each of the following...Ch. 6 - Prob. 6.19EPCh. 6 - Prob. 6.20EPCh. 6 - Prob. 6.21EPCh. 6 - Prob. 6.22EPCh. 6 - Prob. 6.23EPCh. 6 - Prob. 6.24EPCh. 6 - Prob. 6.25EPCh. 6 - Classify each of the following compounds as a 1...Ch. 6 - Prob. 6.27EPCh. 6 - Prob. 6.28EPCh. 6 - Prob. 6.29EPCh. 6 - Prob. 6.30EPCh. 6 - Prob. 6.31EPCh. 6 - Prob. 6.32EPCh. 6 - Prob. 6.33EPCh. 6 - Prob. 6.34EPCh. 6 - Determine the maximum number of hydrogen bonds...Ch. 6 - Prob. 6.36EPCh. 6 - Although they have similar molecular masses (73...Ch. 6 - Prob. 6.38EPCh. 6 - Prob. 6.39EPCh. 6 - Prob. 6.40EPCh. 6 - Show the structures of the missing substance(s) in...Ch. 6 - Prob. 6.42EPCh. 6 - Prob. 6.43EPCh. 6 - Prob. 6.44EPCh. 6 - Prob. 6.45EPCh. 6 - Prob. 6.46EPCh. 6 - Prob. 6.47EPCh. 6 - Prob. 6.48EPCh. 6 - Prob. 6.49EPCh. 6 - Prob. 6.50EPCh. 6 - Prob. 6.51EPCh. 6 - Prob. 6.52EPCh. 6 - Prob. 6.53EPCh. 6 - Prob. 6.54EPCh. 6 - Prob. 6.55EPCh. 6 - Prob. 6.56EPCh. 6 - Prob. 6.57EPCh. 6 - Prob. 6.58EPCh. 6 - Prob. 6.59EPCh. 6 - Prob. 6.60EPCh. 6 - Prob. 6.61EPCh. 6 - Prob. 6.62EPCh. 6 - Prob. 6.63EPCh. 6 - Prob. 6.64EPCh. 6 - Prob. 6.65EPCh. 6 - Prob. 6.66EPCh. 6 - Prob. 6.67EPCh. 6 - Prob. 6.68EPCh. 6 - Prob. 6.69EPCh. 6 - Prob. 6.70EPCh. 6 - Prob. 6.71EPCh. 6 - Prob. 6.72EPCh. 6 - Prob. 6.73EPCh. 6 - Prob. 6.74EPCh. 6 - Name each of the salts in Problem 17-71. a....Ch. 6 - Prob. 6.76EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Prob. 6.78EPCh. 6 - Prob. 6.79EPCh. 6 - Prob. 6.80EPCh. 6 - Prob. 6.81EPCh. 6 - Prob. 6.82EPCh. 6 - Prob. 6.83EPCh. 6 - Prob. 6.84EPCh. 6 - Prob. 6.85EPCh. 6 - Prob. 6.86EPCh. 6 - Prob. 6.87EPCh. 6 - Prob. 6.88EPCh. 6 - Prob. 6.89EPCh. 6 - Prob. 6.90EPCh. 6 - Prob. 6.91EPCh. 6 - Indicate whether each of the following statements...Ch. 6 - Prob. 6.93EPCh. 6 - Prob. 6.94EPCh. 6 - Prob. 6.95EPCh. 6 - Prob. 6.96EPCh. 6 - Prob. 6.97EPCh. 6 - Prob. 6.98EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Prob. 6.100EPCh. 6 - Classify each of the following amides as...Ch. 6 - Classify each of the following amides as...Ch. 6 - Prob. 6.103EPCh. 6 - Prob. 6.104EPCh. 6 - Prob. 6.105EPCh. 6 - Prob. 6.106EPCh. 6 - Prob. 6.107EPCh. 6 - Assign an IUPAC name to each of the following...Ch. 6 - Prob. 6.109EPCh. 6 - Prob. 6.110EPCh. 6 - Prob. 6.111EPCh. 6 - Prob. 6.112EPCh. 6 - Prob. 6.113EPCh. 6 - Prob. 6.114EPCh. 6 - Prob. 6.115EPCh. 6 - Prob. 6.116EPCh. 6 - Prob. 6.117EPCh. 6 - Prob. 6.118EPCh. 6 - Prob. 6.119EPCh. 6 - Prob. 6.120EPCh. 6 - Prob. 6.121EPCh. 6 - Prob. 6.122EPCh. 6 - Prob. 6.123EPCh. 6 - Prob. 6.124EPCh. 6 - Prob. 6.125EPCh. 6 - Prob. 6.126EPCh. 6 - Prob. 6.127EPCh. 6 - Prob. 6.128EPCh. 6 - Prob. 6.129EPCh. 6 - Prob. 6.130EPCh. 6 - Prob. 6.131EPCh. 6 - Prob. 6.132EPCh. 6 - Prob. 6.133EPCh. 6 - Prob. 6.134EPCh. 6 - Prob. 6.135EPCh. 6 - Prob. 6.136EPCh. 6 - Prob. 6.137EPCh. 6 - Prob. 6.138EPCh. 6 - Prob. 6.139EPCh. 6 - Prob. 6.140EPCh. 6 - Prob. 6.141EPCh. 6 - Prob. 6.142EPCh. 6 - Prob. 6.143EPCh. 6 - Prob. 6.144EPCh. 6 - Prob. 6.145EPCh. 6 - Draw the structure of the nitrogen-containing...Ch. 6 - Prob. 6.147EPCh. 6 - Prob. 6.148EPCh. 6 - Prob. 6.149EPCh. 6 - Prob. 6.150EPCh. 6 - Prob. 6.151EPCh. 6 - Prob. 6.152EPCh. 6 - Prob. 6.153EPCh. 6 - Prob. 6.154EP
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