“Parent” amine can be regenerated from the given salt or not has to be indicated. Concept Introduction: Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base. Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion. When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below, Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

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9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00

Assign all the carbons

C 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

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Answer 5

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 6

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 7

Chapter 6, Problem 6.73EP

(a)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 8

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 9

(b)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 10

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 11

(c)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 12

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 13

(d)

Interpretation Introduction

Interpretation:

“Parent” amine can be regenerated from the given salt or not has to be indicated.

Concept Introduction:

Quaternary ammonium salt is the one that has four carbon atoms attached to the nitrogen atom. This is formed by the reaction of tertiary amine with alkyl halide in presence of a strong base.

Neutralization reaction is the one that takes place between an acid and a base to give salt as product. As amines are bases due to the amino group in it, the reaction with inorganic acid or carboxylic acid gives salt as product. The salt formed is an amine salt. Proton is donated from the acid to the nitrogen atom which acts as a proton acceptor. In simple words, it can be said that in an amine‑acid reaction, the acid loses a hydrogen ion and amine gains a hydrogen ion.

When a strong base is added to the amine salt, the parent amine can be obtained. This is a reverse reaction of the amine salt formation reaction. These reactions can be represented as shown below,

Quaternary ammonium salt does not give the “parent” amine when treated with a strong base as there is no possibility of deprotonation to take place.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6.1 - Prob. 1QQ Ch. 6.1 - Prob. 2QQ Ch. 6.2 - Prob. 1QQ Ch. 6.2 - Prob. 2QQ Ch. 6.2 - Prob. 3QQ Ch. 6.2 - Prob. 4QQ Ch. 6.3 - Prob. 1QQ Ch. 6.3 - Prob. 2QQ Ch. 6.3 - Prob. 3QQ Ch. 6.3 - Prob. 4QQ

Solution Summary: The author explains that a hydrogen ion is attached to the nitrogen atom in quaternary ammonium salt, which is formed by the reaction of tertiary amine with alkyl halide

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