Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 6, Problem 6H.1BST
Interpretation Introduction

Interpretation:

The pH of the solution that results from the addition of the further 2.0 mL of the HCl(aq) titrant to the analyte has to be calculated.

pH definition:

The concentration of hydrogen ion is measured using pH scale.  The acidity of aqueous solution is expressed by pH scale.

The pH of a solution is defined as the negative base -10 logarithm of the hydrogen or hydronium ion concentration.

  pH=-log[H3O+]

On rearranging, the concentration of hydrogen ion [H+] can be calculated using pH as follows,

  [H+]=10-pH

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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!

Chapter 6 Solutions

Chemical Principles: The Quest for Insight

Ch. 6 - Prob. 6A.5ECh. 6 - Prob. 6A.6ECh. 6 - Prob. 6A.7ECh. 6 - Prob. 6A.8ECh. 6 - Prob. 6A.9ECh. 6 - Prob. 6A.10ECh. 6 - Prob. 6A.11ECh. 6 - Prob. 6A.12ECh. 6 - Prob. 6A.13ECh. 6 - Prob. 6A.14ECh. 6 - Prob. 6A.15ECh. 6 - Prob. 6A.16ECh. 6 - Prob. 6A.17ECh. 6 - Prob. 6A.18ECh. 6 - Prob. 6A.19ECh. 6 - Prob. 6A.20ECh. 6 - Prob. 6A.21ECh. 6 - Prob. 6A.22ECh. 6 - Prob. 6A.23ECh. 6 - Prob. 6A.24ECh. 6 - Prob. 6B.1ASTCh. 6 - Prob. 6B.1BSTCh. 6 - Prob. 6B.2ASTCh. 6 - Prob. 6B.2BSTCh. 6 - Prob. 6B.3ASTCh. 6 - Prob. 6B.3BSTCh. 6 - Prob. 6B.1ECh. 6 - Prob. 6B.2ECh. 6 - Prob. 6B.3ECh. 6 - Prob. 6B.4ECh. 6 - Prob. 6B.5ECh. 6 - Prob. 6B.6ECh. 6 - Prob. 6B.7ECh. 6 - Prob. 6B.8ECh. 6 - Prob. 6B.9ECh. 6 - Prob. 6B.10ECh. 6 - Prob. 6B.11ECh. 6 - Prob. 6B.12ECh. 6 - Prob. 6C.1ASTCh. 6 - Prob. 6C.1BSTCh. 6 - Prob. 6C.2ASTCh. 6 - Prob. 6C.2BSTCh. 6 - Prob. 6C.3ASTCh. 6 - Prob. 6C.3BSTCh. 6 - Prob. 6C.1ECh. 6 - Prob. 6C.2ECh. 6 - Prob. 6C.3ECh. 6 - Prob. 6C.4ECh. 6 - Prob. 6C.5ECh. 6 - Prob. 6C.6ECh. 6 - Prob. 6C.7ECh. 6 - Prob. 6C.8ECh. 6 - Prob. 6C.9ECh. 6 - Prob. 6C.10ECh. 6 - Prob. 6C.11ECh. 6 - Prob. 6C.12ECh. 6 - Prob. 6C.13ECh. 6 - Prob. 6C.14ECh. 6 - Prob. 6C.15ECh. 6 - Prob. 6C.16ECh. 6 - Prob. 6C.17ECh. 6 - Prob. 6C.18ECh. 6 - Prob. 6C.19ECh. 6 - Prob. 6C.20ECh. 6 - Prob. 6C.21ECh. 6 - Prob. 6C.22ECh. 6 - Prob. 6D.1ASTCh. 6 - Prob. 6D.1BSTCh. 6 - Prob. 6D.2ASTCh. 6 - Prob. 6D.2BSTCh. 6 - Prob. 6D.3ASTCh. 6 - Prob. 6D.3BSTCh. 6 - Prob. 6D.4ASTCh. 6 - Prob. 6D.4BSTCh. 6 - Prob. 6D.5ASTCh. 6 - Prob. 6D.5BSTCh. 6 - Prob. 6D.6ASTCh. 6 - Prob. 6D.6BSTCh. 6 - Prob. 6D.1ECh. 6 - Prob. 6D.2ECh. 6 - Prob. 6D.3ECh. 6 - Prob. 6D.4ECh. 6 - Prob. 6D.5ECh. 6 - Prob. 6D.6ECh. 6 - Prob. 6D.7ECh. 6 - Prob. 6D.8ECh. 6 - Prob. 6D.9ECh. 6 - Prob. 6D.11ECh. 6 - Prob. 6D.12ECh. 6 - Prob. 6D.13ECh. 6 - Prob. 6D.14ECh. 6 - Prob. 6D.15ECh. 6 - Prob. 6D.16ECh. 6 - Prob. 6D.17ECh. 6 - Prob. 6D.18ECh. 6 - Prob. 6D.19ECh. 6 - Prob. 6D.20ECh. 6 - Prob. 6D.21ECh. 6 - Prob. 6D.22ECh. 6 - Prob. 6E.1ASTCh. 6 - Prob. 6E.1BSTCh. 6 - Prob. 6E.2ASTCh. 6 - Prob. 6E.2BSTCh. 6 - Prob. 6E.3ASTCh. 6 - Prob. 6E.1ECh. 6 - Prob. 6E.2ECh. 6 - Prob. 6E.3ECh. 6 - Prob. 6E.4ECh. 6 - Prob. 6E.5ECh. 6 - Prob. 6E.6ECh. 6 - Prob. 6E.7ECh. 6 - Prob. 6E.8ECh. 6 - Prob. 6E.9ECh. 6 - Prob. 6E.10ECh. 6 - Prob. 6E.11ECh. 6 - Prob. 6E.12ECh. 6 - Prob. 6E.13ECh. 6 - Prob. 6E.14ECh. 6 - Prob. 6E.15ECh. 6 - Prob. 6E.16ECh. 6 - Prob. 6E.17ECh. 6 - Prob. 6E.18ECh. 6 - Prob. 6F.1ASTCh. 6 - Prob. 6F.1BSTCh. 6 - Prob. 6F.2ASTCh. 6 - Prob. 6F.2BSTCh. 6 - Prob. 6F.1ECh. 6 - Prob. 6F.2ECh. 6 - Prob. 6F.3ECh. 6 - Prob. 6F.4ECh. 6 - Prob. 6F.5ECh. 6 - Prob. 6F.6ECh. 6 - Prob. 6F.7ECh. 6 - Prob. 6F.9ECh. 6 - Prob. 6F.10ECh. 6 - Prob. 6G.1ASTCh. 6 - Prob. 6G.1BSTCh. 6 - Prob. 6G.2ASTCh. 6 - Prob. 6G.2BSTCh. 6 - Prob. 6G.3ASTCh. 6 - Prob. 6G.3BSTCh. 6 - Prob. 6G.4ASTCh. 6 - Prob. 6G.4BSTCh. 6 - Prob. 6G.1ECh. 6 - Prob. 6G.3ECh. 6 - Prob. 6G.4ECh. 6 - Prob. 6G.5ECh. 6 - Prob. 6G.6ECh. 6 - Prob. 6G.7ECh. 6 - Prob. 6G.8ECh. 6 - Prob. 6G.9ECh. 6 - Prob. 6G.11ECh. 6 - Prob. 6G.12ECh. 6 - Prob. 6G.13ECh. 6 - Prob. 6G.14ECh. 6 - Prob. 6G.15ECh. 6 - Prob. 6G.16ECh. 6 - Prob. 6G.19ECh. 6 - Prob. 6G.20ECh. 6 - Prob. 6H.1ASTCh. 6 - Prob. 6H.1BSTCh. 6 - Prob. 6H.2ASTCh. 6 - Prob. 6H.2BSTCh. 6 - Prob. 6H.3ASTCh. 6 - Prob. 6H.3BSTCh. 6 - Prob. 6H.4ASTCh. 6 - Prob. 6H.4BSTCh. 6 - Prob. 6H.5ASTCh. 6 - Prob. 6H.5BSTCh. 6 - Prob. 6H.1ECh. 6 - Prob. 6H.3ECh. 6 - Prob. 6H.9ECh. 6 - Prob. 6H.10ECh. 6 - Prob. 6H.15ECh. 6 - Prob. 6H.16ECh. 6 - Prob. 6H.21ECh. 6 - Prob. 6H.22ECh. 6 - Prob. 6H.23ECh. 6 - Prob. 6H.24ECh. 6 - Prob. 6H.25ECh. 6 - Prob. 6H.26ECh. 6 - Prob. 6H.27ECh. 6 - Prob. 6H.28ECh. 6 - Prob. 6H.29ECh. 6 - Prob. 6H.30ECh. 6 - Prob. 6H.31ECh. 6 - Prob. 6H.32ECh. 6 - Prob. 6I.1ASTCh. 6 - Prob. 6I.1BSTCh. 6 - Prob. 6I.2ASTCh. 6 - Prob. 6I.2BSTCh. 6 - Prob. 6I.3ASTCh. 6 - Prob. 6I.3BSTCh. 6 - Prob. 6I.4ASTCh. 6 - Prob. 6I.4BSTCh. 6 - Prob. 6I.1ECh. 6 - Prob. 6I.2ECh. 6 - Prob. 6I.3ECh. 6 - Prob. 6I.4ECh. 6 - Prob. 6I.5ECh. 6 - Prob. 6I.6ECh. 6 - Prob. 6I.7ECh. 6 - Prob. 6I.8ECh. 6 - Prob. 6I.9ECh. 6 - Prob. 6I.10ECh. 6 - Prob. 6I.11ECh. 6 - Prob. 6I.12ECh. 6 - Prob. 6J.1ASTCh. 6 - Prob. 6J.1BSTCh. 6 - Prob. 6J.2ASTCh. 6 - Prob. 6J.2BSTCh. 6 - Prob. 6J.1ECh. 6 - Prob. 6J.2ECh. 6 - Prob. 6J.3ECh. 6 - Prob. 6J.4ECh. 6 - Prob. 6J.9ECh. 6 - Prob. 6J.10ECh. 6 - Prob. 6J.11ECh. 6 - Prob. 6J.15ECh. 6 - Prob. 6J.17ECh. 6 - Prob. 6K.1ASTCh. 6 - Prob. 6K.1BSTCh. 6 - Prob. 6K.2ASTCh. 6 - Prob. 6K.2BSTCh. 6 - Prob. 6K.1ECh. 6 - Prob. 6K.2ECh. 6 - Prob. 6K.3ECh. 6 - Prob. 6K.4ECh. 6 - Prob. 6K.5ECh. 6 - Prob. 6K.6ECh. 6 - Prob. 6K.7ECh. 6 - Prob. 6K.8ECh. 6 - Prob. 6L.1ASTCh. 6 - Prob. 6L.1BSTCh. 6 - Prob. 6L.2ASTCh. 6 - Prob. 6L.2BSTCh. 6 - Prob. 6L.3ASTCh. 6 - Prob. 6L.3BSTCh. 6 - Prob. 6L.1ECh. 6 - Prob. 6L.2ECh. 6 - Prob. 6L.3ECh. 6 - Prob. 6L.4ECh. 6 - Prob. 6L.5ECh. 6 - Prob. 6L.7ECh. 6 - Prob. 6L.9ECh. 6 - Prob. 6M.1ASTCh. 6 - Prob. 6M.1BSTCh. 6 - Prob. 6M.2ASTCh. 6 - Prob. 6M.2BSTCh. 6 - Prob. 6M.3ASTCh. 6 - Prob. 6M.3BSTCh. 6 - Prob. 6M.4ASTCh. 6 - Prob. 6M.4BSTCh. 6 - Prob. 6M.1ECh. 6 - Prob. 6M.2ECh. 6 - Prob. 6M.9ECh. 6 - Prob. 6M.10ECh. 6 - Prob. 6N.1ASTCh. 6 - Prob. 6N.1BSTCh. 6 - Prob. 6N.2ASTCh. 6 - Prob. 6N.2BSTCh. 6 - Prob. 6N.3BSTCh. 6 - Prob. 6N.4ASTCh. 6 - Prob. 6N.4BSTCh. 6 - Prob. 6N.1ECh. 6 - Prob. 6N.2ECh. 6 - Prob. 6N.5ECh. 6 - Prob. 6N.6ECh. 6 - Prob. 6N.7ECh. 6 - Prob. 6N.9ECh. 6 - Prob. 6N.10ECh. 6 - Prob. 6N.11ECh. 6 - Prob. 6N.12ECh. 6 - Prob. 6N.21ECh. 6 - Prob. 6N.23ECh. 6 - Prob. 6O.1ASTCh. 6 - Prob. 6O.1BSTCh. 6 - Prob. 6O.2ASTCh. 6 - Prob. 6O.2BSTCh. 6 - Prob. 6O.3ASTCh. 6 - Prob. 6O.3BSTCh. 6 - Prob. 6O.4ASTCh. 6 - Prob. 6O.4BSTCh. 6 - Prob. 6O.1ECh. 6 - Prob. 6O.2ECh. 6 - Prob. 6O.3ECh. 6 - Prob. 6O.4ECh. 6 - Prob. 6O.5ECh. 6 - Prob. 6O.6ECh. 6 - Prob. 6O.7ECh. 6 - Prob. 6O.8ECh. 6 - Prob. 6O.9ECh. 6 - Prob. 6O.10ECh. 6 - Prob. 6O.11ECh. 6 - Prob. 6O.12ECh. 6 - Prob. 6O.13ECh. 6 - Prob. 6O.14ECh. 6 - Prob. 6O.15ECh. 6 - Prob. 6O.16ECh. 6 - Prob. 6.1ECh. 6 - Prob. 6.3ECh. 6 - Prob. 6.4ECh. 6 - Prob. 6.5ECh. 6 - Prob. 6.6ECh. 6 - Prob. 6.8ECh. 6 - Prob. 6.9ECh. 6 - Prob. 6.10ECh. 6 - Prob. 6.11ECh. 6 - Prob. 6.12ECh. 6 - Prob. 6.13ECh. 6 - Prob. 6.14ECh. 6 - Prob. 6.25ECh. 6 - Prob. 6.40ECh. 6 - Prob. 6.41ECh. 6 - Prob. 6.43ECh. 6 - Prob. 6.45ECh. 6 - Prob. 6.46ECh. 6 - Prob. 6.47ECh. 6 - Prob. 6.51ECh. 6 - Prob. 6.53ECh. 6 - Prob. 6.65ECh. 6 - Prob. 6.75ECh. 6 - Prob. 6.77E
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