Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 6, Problem 6.9P
Given each of the following values, is the starting material or product lower in energy?
a.
b.
c.
d.
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Students have asked these similar questions
a.Which value corresponds to a negative value of ΔGo: Keq = 10−2 or Keq = 102?
b.In a unimolecular reaction with five times as much starting material as product at equilibrium, what is the value of Keq? Is ΔGo positive or negative?
c.Which value corresponds to a larger Keq: ΔGo = −8 kJ/mol or ΔGo = 20 kJ/mol?
Consider the reaction: A + B. When this reaction
reaches equilibrium, which quantity equals zero?
The equilibrium constant, Keg
The free energy change, AG
The concentration of A and B
O The enthalpy change, AH
XY ↔ X + Y Kc = 1.1 x 10-1 at 125C ΔH = -24.5 kJ/mol rxn.
b. A catalyst is added to the reaction. a.How will the concentrations of the reactants and products at equilibrium change? Explain your reasoning.b. How will the addition of a catalyst affect the enthalpy of the reaction? Explain your reasoning. c.The temperature of the reaction is decreased from 125 oC to 25 oC. In the boxes like the ones shown here, draw a possible new molecular diagram to represent any changes that would occur in concentrations. d. Will the equilibrium constant value increase, decrease, or remain the same when the temperature is decreased? Explain your reasoning. e. How will lowering the temperature affect the enthalpy of the reaction? Explain your reasoning.
Chapter 6 Solutions
Organic Chemistry
Ch. 6 - Prob. 6.1PCh. 6 - By taking into account electronegativity...Ch. 6 - Use curved arrows to show the movement of...Ch. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - aWhich Keq corresponds to a negative value of G,...Ch. 6 - Given each of the following values, is the...Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...
Ch. 6 - Prob. 6.11PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.20PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.22PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.27PCh. 6 - Draw the products of each reaction by following...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.37PCh. 6 - At 25 C, the energy difference Go for the...Ch. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - 6.44 Consider the following reaction: .
Use curved...Ch. 6 - Prob. 6.43PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.57P
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- Using values of fH and S, calculate rG for each of the following reactions at 25 C. (a) 2 Na(s) + 2 H2O() 2 NaOH(aq) + H2(g) (b) 6 C(graphite) + 3 H2(g) C6H6() Which of these reactions is (are) predicted to be product-favored at equilibrium? Are the reactions enthalpy- or entropy-driven?arrow_forwardSodium chloride is added to water (at 25C) until it is saturated. Calculate the Cl concentration in such a solution. Species G(kJ/mol) NaCl(s) 384 Na+(aq) 262 Cl(aq) 131arrow_forwardWrite a chemical equation for each process and classify each as reactant-favored or product-favored. (a) A puddle of water evaporates on a summer day. (b) Silicon dioxide (sand) decomposes to the elements Silicon and oxygen. (c) Paper, which is mainly cellulose (C6H10O5)n, bums at a temperature of 451 F. (d) A pinch of sugar dissolves in water at room temperature.arrow_forward
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