Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
bartleby

Concept explainers

Question
Book Icon
Chapter 6, Problem 6.11P
Interpretation Introduction

(a)

Interpretation: Whether the starting material or product is favored at equilibrium is to be predicted on the basis of the given value of ΔH°.

Concept introduction: The change in Gibbs free energy and enthalpy is represented by ΔG° and ΔH° respectively. They both are state functions. The relation of ΔG° and ΔH° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction, whereas the change in enthalpy describes the relative bond strength in the substance.

Interpretation Introduction

(b)

Interpretation: The starting material or product which is favored at equilibrium is to be identified.

Concept introduction: The change in Gibbs free energy and enthalpy is represented by ΔG° and ΔH° respectively. They both are state functions. The relation of ΔG° and ΔH° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction, whereas the change in enthalpy describes the relative bond strength in the substance.

Blurred answer
Students have asked these similar questions
Calculate ΔH° for each reaction. a. HO• + CH4 → •CH3 + H2O b. CH3OH + HBr → CH3Br + H2O
Now consider the following reaction: C2H5OH + 3O2→2CO2+ 3H2O ,ΔH=−1370 kJ/mol What is the enthalpy for the reaction reversed? reaction 1 reversed: 2CO2 + 3H2O→C2H5OH + 3O2
The ΔHac of nitrogen dioxide is -937.86 kJ/mole. The ΔHf of nitrogen dioxide is +33.2 kJ/mole. Propose a reasonable explanation for this difference

Chapter 6 Solutions

Organic Chemistry

Ch. 6 - Prob. 6.11PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.20PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.22PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.27PCh. 6 - Draw the products of each reaction by following...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.37PCh. 6 - At 25 C, the energy difference Go for the...Ch. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - 6.44 Consider the following reaction: . Use curved...Ch. 6 - Prob. 6.43PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.57P
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Chemistry In Focus
Chemistry
ISBN:9781305084476
Author:Tro, Nivaldo J., Neu, Don.
Publisher:Cengage Learning