Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 6, Problem 6.10P
The equilibrium constant for the conversion of the axial to the equatorial conformation of methoxycyclohexane is
a. Given these data, which conformation is present in the larger amount at equilibrium?
b. Is
c. From the values in Table
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Given the following data:
4C(s) + 4H2(g) + O2(g) → CH3CH2OCOCH3(l)
ΔH°=-480.0 kJ
CH3CH2OH(l) + O2(g) → CH3COOH(l) + H2O(l)
ΔH°=-492.0 kJ
2C(s) + 3H2(g) + 1/2O2(g) → CH3CH2OH(l)
ΔH°=-278.0 kJ
H2(g) + 1/2O2(g) → H2O(l)
ΔH°=-286.0 kJ
calculate ΔH° for the reaction:CH3COOH(l) + CH3CH2OH(l) → CH3CH2OCOCH3(l) + H2O(l)
Given the following data:
2 C6H6(l) + 15 O2(g) → 12 CO2(g) + 6 H2O(l) ΔG0= -6399 kJ
C(s) + O2(g) → CO2(g) ΔG0= -394 kJ
H2(g) + ½O2(g) → H2O(l) ΔG0= -237 kJ
Calculate the ΔG0rxn for the reaction
6 C(s) + 3 H2(g) → C6H6(l)
Difluoroacetylene (C2F2) gas has a ΔHf° = 241.2 kJ/mole and a a ΔGf° = 191.2 kJ/mole. Hexafluorobenzene(C6F6) gas has a ΔHf° = 132.8 kJ/mole and a a ΔGf° = 78.2 kJ/mole. For the following reaction:
C6F6(g) ⇌ 3C2F2(g)
Calculate:a) The ΔS for the reaction at 25 °Cb) The equilibrium constant K at 25 °Cc) The equilibrium constant K at 2700 °C (assuming there is no temperature dependance on ΔH and ΔS)
Chapter 6 Solutions
Organic Chemistry
Ch. 6 - Prob. 6.1PCh. 6 - By taking into account electronegativity...Ch. 6 - Use curved arrows to show the movement of...Ch. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - aWhich Keq corresponds to a negative value of G,...Ch. 6 - Given each of the following values, is the...Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...
Ch. 6 - Prob. 6.11PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.20PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.22PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.27PCh. 6 - Draw the products of each reaction by following...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.37PCh. 6 - At 25 C, the energy difference Go for the...Ch. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - 6.44 Consider the following reaction: .
Use curved...Ch. 6 - Prob. 6.43PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.57P
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