ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Question
Chapter 6, Problem 6.57P
Interpretation Introduction
Interpretation: The reason for the different
Concept introduction: The change in Gibbs free energy is represented by
If the
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Esterication is the reaction of a carboxylic acid (RCOOH) with an alcohol (R'OH) to form an ester (RCOOR') with loss of water. Equation [1] is an example of an intermolecular esterication reaction. Equation [2] is an example of an intramolecular esterication reaction; that is, the carboxylic acid and alcohol are contained in the same starting material, forming a cyclic ester as product. The equilibrium constants for both reactions are given. Explain why Keq is different for these two apparently similar reactions.
In an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.
b)
Ho わ-fャコーfつ
Koc
5. Complete the following oxidation reactions for alcohols. Draw the structure of the product.
Name the reactant and identify the type of compound formed in the product.
CHっーCHューC
OH
b)
CHy
CH3
Chapter 6 Solutions
ORGANIC CHEMISTRY
Ch. 6 - Problem 6.1 Classify each transformation as...Ch. 6 - Prob. 6.2PCh. 6 - Problem 6.3 By taking into account...Ch. 6 - Problem 6.4 Use curved arrows to show the movement...Ch. 6 - Problem 6.5 Follow the curved arrows and draw the...Ch. 6 - Prob. 6.6PCh. 6 - Problem 6.7 Use the values in Table 6.2 to...Ch. 6 - Prob. 6.8PCh. 6 - aWhich Keq corresponds to a negative value of G,...Ch. 6 - Given each of the following values, is the...
Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...Ch. 6 - Prob. 6.13PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.22PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.24PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.29PCh. 6 - 6.30 Draw the products of each reaction by...Ch. 6 - 6.31 (a) Add curved arrows for each step to show...Ch. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Calculate H for each reaction. a HO+CH4CH3+H2O b...Ch. 6 - Homolysis of the indicated CH bond in propene...Ch. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.40PCh. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - 6.44 Consider the following reaction: .
Use curved...Ch. 6 - Prob. 6.45PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.47PCh. 6 - Indicate which factors affect the rate of a...Ch. 6 - Prob. 6.49PCh. 6 - 6.50 The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - The conversion of (CH3)3Cl to (CH3)2C=CH2 can...Ch. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.59P
Knowledge Booster
Similar questions
- What functional group distinguishes each of the following hydrocarbon derivatives? a. halohydrocarbons b. alcohols c. ethers d. aldehydes e. ketones f. carboxylic acids g. esters h. amines Give examples of each functional group. What prefix or suffix is used to name each functional group? What are the bond angles in each? Describe the bonding in each functional group. What is the difference between a primary, secondary, and tertiary alcohol? For the functional groups in ah, when is a number required to indicate the position of the functional group? Carboxylic acids are often written as RCOOH. What does COOH indicate and what does R indicate? Aldehydes are sometimes written as RCHO. What does CHO indicate?arrow_forwardWrite the chemical equation for the decarboxylation of 2-methyl-propanoic acid. Which is formula of this rule of reaction?arrow_forwardBoth aldehydes and ketones contain carbonyl groups. In aldehydes, the carbonyl carbon atom is bonded to a hydrogen atom, whereas in ketones, the carbonyl carbon atom is bonded to another carbon atom. Select the true statements about aldehydes and ketones. - Ketones have lower boiling points than alcohols of similar size. - Aldehydes contain a carbon–oxygen double bond. - Butanal has a higher boiling point than 2-butanol. - Aldehydes with more than five carbon atoms are soluble in water, but not organic solvents. - Both aldehydes and ketones can hydrogen bond with water molecules. - Propanal is a gas at room temperature, whereas formaldehyde (methanal) is a liquid at room temperature.arrow_forward
- Arrange the following compounds in decreasing order of boiling point. Highest Boiling Point 1 Ethanoic acid (carboxylic acid) 2 Ethanamide (amide) 3 propan-1-ol (alcohol) 4 n-butane (alkane) Lowest Boiling Pointarrow_forwardIdentify each organic compound as an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and provide a name for the compound. CH3 b. CH;-CH2-CH-CH2-0-CH2-CH;arrow_forward1. Most margarines have been hydrogenated to maintain a soft, homogeneous mixture. While the product is easy to spread, this has made the product an unhealthy choice. A hydrogenation reaction is used to convert an alkene to an alkane. a carboxylic acid to an aldehyde. an alkene to a ketone an aromatic hydrocarbon to a linear hydrocarbonarrow_forward
- Classify each of the following molecules as alcohol,aldehyde, ketone, carboxylic acid, amine, or ether.arrow_forwardPrepare CH3COOC2HS, ethyl acetate, using ethyl alcohol. Write the chemical reaction.arrow_forwardConsider the following reactions: When C5H12 is reacted with Cl2(g) in the presence of ultraviolet light, four different monochlorination products form. What is the structure of C5H12 in this reaction? When C4H8 is reacted with H2O, a tertiary alcohol is produced as the major product. What is the structure of C4H8 in this reaction? When C7H12 is reacted with HCl, 1-chloro-1-methylcyclohexane is produced as the major product. What are the two possible structures for C7H12 in this reaction? When a hydrocarbon is reacted with water and the major product of this reaction is then oxidized, acetone (2-propanone) is produced. What is the structure of the hydrocarbon in this reaction? When C5H12O is oxidized, a carboxylic acid is produced. What are the possible structures for C5H12O in this reaction?arrow_forward
- LSaxw_byUjt4NKKTEABPFImknTAVIxeSATH3-MO9AEbrFOXuga ponse TUIse The structure of glycogen is very similar to that of amylose Secondary alcohols are readily oxidized with common oxidizing agents to carboxylic acids Amines react with strong acids such as HCI, to form ammonium salts In general, oils come from animal sources and fats from vegetable sources Amines are weak bases, they are considerably more basic than alcohols, and water Carboxylic acids are less acidic than alcohols Steroids are lipids that do not contain fatty acids Alkylamines have boiling points are higher than those of alkanes, but lower than those of alcohols 4- Tio druck & 1 8. 9. Y ! OX { Hi J K : NI pause O O O O O O O O OOarrow_forwardI need help with number 9 part B. Which was the formula of the oxidizing agents, such as CrO3, MnO4 - , or enzymes can oxidized primary alcohols to produce carboxylic acids. Draw the structure of the carboxylic acid that is formed when the alcohol shown below is oxidized?arrow_forwardComplete the organic reaction.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning