ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Chapter 6, Problem 6.35P
Calculate
a)
b)
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Calculate the enthalpy for the reaction.
ΔH CH2=CH2, 62 kcal/mol
H-Cl, 103 kcal/mol
CH3 CH2-H, 101 kcal/mol
CH3CH2-Cl, 85 kcal/mol
Calculate A,H for the following reaction:
5C(s) + 6H2(9) → C5H12(1)
Use the following reactions and given ArH's.
C5H12 (1) + 8 O2(g) → 5CO2(g) + 6H2O(g), A;H = -3505.8 kJ mol
C(s) + 02(g) → CO2(g), ArH = -393.5 kJ mol1
2H2(g) + O2(9) → 2H2O(g) , A¡H = -483.5 kJ mol
Calculate the value (calories) for the heat of reaction.
NaOH(s) ─HCl→ Na+(aq) + Cl-(aq) + H2O(l)
Useful Information:
Volume of HCl: .055 LVolume of water: .045 LVolume total: .1 LMolarity of HCl: 2.12 MMass of NaOH: 4.00 gΔT for reaction C: 21.3°C
Specific Heat Capacity of Sodium Chloride: .94 cal g^-1 C^-1
Chapter 6 Solutions
ORGANIC CHEMISTRY
Ch. 6 - Problem 6.1 Classify each transformation as...Ch. 6 - Prob. 6.2PCh. 6 - Problem 6.3 By taking into account...Ch. 6 - Problem 6.4 Use curved arrows to show the movement...Ch. 6 - Problem 6.5 Follow the curved arrows and draw the...Ch. 6 - Prob. 6.6PCh. 6 - Problem 6.7 Use the values in Table 6.2 to...Ch. 6 - Prob. 6.8PCh. 6 - aWhich Keq corresponds to a negative value of G,...Ch. 6 - Given each of the following values, is the...
Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...Ch. 6 - Prob. 6.13PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.22PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.24PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.29PCh. 6 - 6.30 Draw the products of each reaction by...Ch. 6 - 6.31 (a) Add curved arrows for each step to show...Ch. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Calculate H for each reaction. a HO+CH4CH3+H2O b...Ch. 6 - Homolysis of the indicated CH bond in propene...Ch. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.40PCh. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - 6.44 Consider the following reaction: .
Use curved...Ch. 6 - Prob. 6.45PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.47PCh. 6 - Indicate which factors affect the rate of a...Ch. 6 - Prob. 6.49PCh. 6 - 6.50 The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - The conversion of (CH3)3Cl to (CH3)2C=CH2 can...Ch. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.59P
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Now consider the following reaction: C2H5OH + 3O2→2CO2+ 3H2O ,ΔH=−1370 kJ/mol What is the enthalpy for the reaction reversed? reaction 1 reversed: 2CO2 + 3H2O→C2H5OH + 3O2arrow_forwardFf.316.arrow_forwardCalculate AH for the reaction NH3 (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (g), from the following data. N2 (g) + O2 (g) → 2 NO (g) ΔΗ - 180.5 kJ / mol N2 (g) + 3 H2 (g) → 2 NH3 (g) /mol AH = - 91. 8 kJ 2 H2 (g) + O2 (g) → 2 H20 (g) AH ΔΗ- - 483. 6 kJ / molarrow_forward
- Calculate Δ Hrxn for Ca(s) + 1/2 O2(g) + CO2(g) → CaCO3(s) given the following set of reactions: Ca(s) + 1/2 O2(g) →CaO(s) ΔH = −635.1 kJ CaCO3(s) →CaO(s) + CO2(g) ΔH = 178.3 kJarrow_forwardAt 10°C, Keq for a reaction is 100. At 30°C, Keq = 10. Does enthalpy increase or decrease during the reaction?arrow_forwardThe reaction that was on the screen when you started and its derivative demonstrate that the reaction enthalpy, ΔH, changes sign when a process is reversed. Consider the reaction H2O(l)→H2O(g), ΔH =44.0kJ What will ΔH be for the reaction if it is reversed?arrow_forward
- S CO₂H Br₂ ACOHarrow_forward2 C,H, +70; 20+2 C0, + 8 H,0 + heat 80 2C,H, +70; 2C+2 CO +2 Co, + 8 H,0 + heat CH, + 50; 3 CO, + 4 H,0 + heat C.H. +70. + CO, - 4 C0, + 4 H.0 + heat The complete combustion of propane gas can be represented as 2 C3Hs +7 02 2 C + 2 CO2 + 8 H20 + heat 2 C3Hs +7 02 2 C + 2 CO + 2 CO2 + 8 H2O + heat C3H8 + 5 02 + 3 CO2 + 4 H20 + heat C3H8 + 702 + CO2 4 CO2 +4 H20 + heatarrow_forwardUse the following equations to calculate the heat of the reaction for the formation of methanol. CH3OH(l) + 3/2 O2(g) → CO2(g) + 2H2O(l) ∆ Ho = -727 kJ C(gr) + O2(g) → CO2(g) ∆ Ho = -394 kJ H2(g) + 1/2 O2(g) → H2O(l) ∆ Ho = -286 kJ Calculate ∆Ho for the following reaction:C(gr) + 2H2(g) + 1/2 O2 → CH3OH(l) methanolUse kJ for your answer.arrow_forward
- Enter your answer in the provided box. You are given the following data: H,(g) → 2H(g) AH° = 436.4 kJ/mol Br2(g) → 2Br(g) AH° = 192.5 kJ/mol H;(g) + Br2(g) → 2HB1(g) AH° = -72.4 kJ/mol Calculate AH for the reaction H(g) + Br(g) → HBr(g) kJ/molarrow_forwardFill in the missing reactant or reagent or product to bring about the following chemical reactions.arrow_forwardCalculate the heat of reaction, ▲H°, for this conversion.arrow_forward
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