ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM
7th Edition
ISBN: 9781319399849
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 5, Problem 5J.9E

(a)

Interpretation Introduction

Interpretation:

The effect of partial pressure of NH3 when NO partial pressure is increased has to be identified.

Concept Introduction:

Le Chatelier's principle:

When a change is applied to a system at equilibrium, the equilibrium will shift against the change. The equilibrium of a system will be affected by the change in temperature, pressure, and concentration.

(b)

Interpretation Introduction

Interpretation:

The effect of partial pressure of O2 when NH3 partial pressure is decreased has to be identified.

Concept Introduction:

Refer part (a).

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Consider the equilibrium4NO2(g) + 6H2 O(g) ⇌ 4NH3(g) + 7O2(g)(a) What is the expression for the equilibrium constant (Kc) of the reaction?(b) How must the concentration of NH3 change to reach equilibrium if the reaction quotient is less than the equilibrium constant?(c) If the reaction were at equilibrium, how would a decrease in pressure (from an increase in the volume of the reaction vessel) affect the pressure of NO2?(d) If the change in the pressure of NO2 is 28 torr as a mixture of the four gases reaches equilibrium, how much will the pressure of O2 change?
(a) Is the dissociation of fluorine molecules into atomicfluorine, F2(g)⇌ 2 F(g) an exothermic or endothermicprocess? (b) If the temperature is raised by 100 K, doesthe equilibrium constant for this reaction increase or decrease? (c) If the temperature is raised by 100 K, doesthe forward rate constant kf increase by a larger or smalleramount than the reverse rate constant kr?
The equilibrium constant for the reaction2 NO(g) + Br2(g) ⇌ 2 NOBr(g)is Kc = 1.3 x 10-2 at 1000 K. (a) At this temperature doesthe equilibrium favor NO and Br2, or does it favor NOBr?(b) Calculate Kc for 2 NOBr(g)⇌ 2 NO(g) + Br2(g).(c) Calculate Kc for NOBr(g)⇌ NO(g) + 1/2 Br2(g).

Chapter 5 Solutions

ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM

Ch. 5 - Prob. 5A.5ECh. 5 - Prob. 5A.6ECh. 5 - Prob. 5A.7ECh. 5 - Prob. 5A.8ECh. 5 - Prob. 5A.11ECh. 5 - Prob. 5B.1ASTCh. 5 - Prob. 5B.1BSTCh. 5 - Prob. 5B.2ASTCh. 5 - Prob. 5B.2BSTCh. 5 - Prob. 5B.3ASTCh. 5 - Prob. 5B.3BSTCh. 5 - Prob. 5B.1ECh. 5 - Prob. 5B.2ECh. 5 - Prob. 5B.3ECh. 5 - Prob. 5B.5ECh. 5 - Prob. 5B.7ECh. 5 - Prob. 5C.1ASTCh. 5 - Prob. 5C.1BSTCh. 5 - Prob. 5C.2ASTCh. 5 - Prob. 5C.2BSTCh. 5 - Prob. 5C.3ASTCh. 5 - Prob. 5C.3BSTCh. 5 - Prob. 5C.1ECh. 5 - Prob. 5C.3ECh. 5 - Prob. 5C.4ECh. 5 - Prob. 5C.5ECh. 5 - Prob. 5C.6ECh. 5 - Prob. 5C.7ECh. 5 - Prob. 5C.8ECh. 5 - Prob. 5C.9ECh. 5 - Prob. 5C.10ECh. 5 - Prob. 5C.11ECh. 5 - Prob. 5C.12ECh. 5 - Prob. 5C.15ECh. 5 - Prob. 5C.16ECh. 5 - Prob. 5D.1ASTCh. 5 - Prob. 5D.1BSTCh. 5 - Prob. 5D.1ECh. 5 - Prob. 5D.2ECh. 5 - Prob. 5D.3ECh. 5 - Prob. 5D.4ECh. 5 - Prob. 5D.5ECh. 5 - Prob. 5D.6ECh. 5 - Prob. 5D.7ECh. 5 - Prob. 5D.8ECh. 5 - Prob. 5D.9ECh. 5 - Prob. 5D.10ECh. 5 - Prob. 5D.11ECh. 5 - Prob. 5D.12ECh. 5 - Prob. 5D.13ECh. 5 - Prob. 5D.14ECh. 5 - Prob. 5D.15ECh. 5 - Prob. 5D.16ECh. 5 - Prob. 5D.18ECh. 5 - Prob. 5D.19ECh. 5 - Prob. 5D.20ECh. 5 - Prob. 5E.1ASTCh. 5 - Prob. 5E.1BSTCh. 5 - Prob. 5E.2ASTCh. 5 - Prob. 5E.2BSTCh. 5 - Prob. 5E.1ECh. 5 - Prob. 5E.2ECh. 5 - Prob. 5E.11ECh. 5 - Prob. 5E.12ECh. 5 - Prob. 5F.1ASTCh. 5 - Prob. 5F.1BSTCh. 5 - Prob. 5F.2ASTCh. 5 - Prob. 5F.2BSTCh. 5 - Prob. 5F.3ASTCh. 5 - Prob. 5F.3BSTCh. 5 - Prob. 5F.4ASTCh. 5 - Prob. 5F.4BSTCh. 5 - Prob. 5F.5ASTCh. 5 - Prob. 5F.5BSTCh. 5 - Prob. 5F.1ECh. 5 - Prob. 5F.2ECh. 5 - Prob. 5F.3ECh. 5 - Prob. 5F.5ECh. 5 - Prob. 5F.7ECh. 5 - Prob. 5F.9ECh. 5 - Prob. 5F.10ECh. 5 - Prob. 5F.11ECh. 5 - Prob. 5F.12ECh. 5 - Prob. 5F.13ECh. 5 - Prob. 5F.14ECh. 5 - Prob. 5F.15ECh. 5 - Prob. 5F.16ECh. 5 - Prob. 5G.1ASTCh. 5 - Prob. 5G.1BSTCh. 5 - Prob. 5G.2ASTCh. 5 - Prob. 5G.2BSTCh. 5 - Prob. 5G.3ASTCh. 5 - Prob. 5G.3BSTCh. 5 - Prob. 5G.4ASTCh. 5 - Prob. 5G.4BSTCh. 5 - Prob. 5G.5ASTCh. 5 - Prob. 5G.5BSTCh. 5 - Prob. 5G.1ECh. 5 - Prob. 5G.2ECh. 5 - Prob. 5G.3ECh. 5 - Prob. 5G.4ECh. 5 - Prob. 5G.7ECh. 5 - Prob. 5G.8ECh. 5 - Prob. 5G.9ECh. 5 - Prob. 5G.11ECh. 5 - Prob. 5G.12ECh. 5 - Prob. 5G.13ECh. 5 - Prob. 5G.14ECh. 5 - Prob. 5G.15ECh. 5 - Prob. 5G.16ECh. 5 - Prob. 5G.17ECh. 5 - Prob. 5G.19ECh. 5 - Prob. 5G.20ECh. 5 - Prob. 5G.21ECh. 5 - Prob. 5G.22ECh. 5 - Prob. 5H.1ASTCh. 5 - Prob. 5H.1BSTCh. 5 - Prob. 5H.2ASTCh. 5 - Prob. 5H.2BSTCh. 5 - Prob. 5H.1ECh. 5 - Prob. 5H.2ECh. 5 - Prob. 5H.3ECh. 5 - Prob. 5H.4ECh. 5 - Prob. 5H.5ECh. 5 - Prob. 5H.6ECh. 5 - Prob. 5I.1ASTCh. 5 - Prob. 5I.1BSTCh. 5 - Prob. 5I.2ASTCh. 5 - Prob. 5I.2BSTCh. 5 - Prob. 5I.3ASTCh. 5 - Prob. 5I.3BSTCh. 5 - Prob. 5I.4ASTCh. 5 - Prob. 5I.4BSTCh. 5 - Prob. 5I.1ECh. 5 - Prob. 5I.2ECh. 5 - Prob. 5I.3ECh. 5 - Prob. 5I.4ECh. 5 - Prob. 5I.5ECh. 5 - Prob. 5I.6ECh. 5 - Prob. 5I.7ECh. 5 - Prob. 5I.9ECh. 5 - Prob. 5I.10ECh. 5 - Prob. 5I.11ECh. 5 - Prob. 5I.12ECh. 5 - Prob. 5I.13ECh. 5 - Prob. 5I.14ECh. 5 - Prob. 5I.15ECh. 5 - Prob. 5I.16ECh. 5 - Prob. 5I.17ECh. 5 - Prob. 5I.18ECh. 5 - Prob. 5I.19ECh. 5 - Prob. 5I.20ECh. 5 - Prob. 5I.21ECh. 5 - Prob. 5I.22ECh. 5 - Prob. 5I.23ECh. 5 - Prob. 5I.24ECh. 5 - Prob. 5I.25ECh. 5 - Prob. 5I.26ECh. 5 - Prob. 5I.27ECh. 5 - Prob. 5I.28ECh. 5 - Prob. 5I.29ECh. 5 - Prob. 5I.30ECh. 5 - Prob. 5I.32ECh. 5 - Prob. 5I.33ECh. 5 - Prob. 5I.34ECh. 5 - Prob. 5I.35ECh. 5 - Prob. 5I.36ECh. 5 - Prob. 5J.1ASTCh. 5 - Prob. 5J.1BSTCh. 5 - Prob. 5J.3ASTCh. 5 - Prob. 5J.3BSTCh. 5 - Prob. 5J.4ASTCh. 5 - Prob. 5J.4BSTCh. 5 - Prob. 5J.5ASTCh. 5 - Prob. 5J.5BSTCh. 5 - Prob. 5J.1ECh. 5 - Prob. 5J.2ECh. 5 - Prob. 5J.3ECh. 5 - Prob. 5J.4ECh. 5 - Prob. 5J.5ECh. 5 - Prob. 5J.6ECh. 5 - Prob. 5J.9ECh. 5 - Prob. 5J.10ECh. 5 - Prob. 5J.11ECh. 5 - Prob. 5J.12ECh. 5 - Prob. 5J.13ECh. 5 - Prob. 5J.17ECh. 5 - Prob. 5.1ECh. 5 - Prob. 5.2ECh. 5 - Prob. 5.3ECh. 5 - Prob. 5.4ECh. 5 - Prob. 5.5ECh. 5 - Prob. 5.6ECh. 5 - Prob. 5.7ECh. 5 - Prob. 5.8ECh. 5 - Prob. 5.9ECh. 5 - Prob. 5.10ECh. 5 - Prob. 5.11ECh. 5 - Prob. 5.12ECh. 5 - Prob. 5.13ECh. 5 - Prob. 5.14ECh. 5 - Prob. 5.15ECh. 5 - Prob. 5.16ECh. 5 - Prob. 5.17ECh. 5 - Prob. 5.19ECh. 5 - Prob. 5.23ECh. 5 - Prob. 5.24ECh. 5 - Prob. 5.25ECh. 5 - Prob. 5.26ECh. 5 - Prob. 5.27ECh. 5 - Prob. 5.28ECh. 5 - Prob. 5.29ECh. 5 - Prob. 5.30ECh. 5 - Prob. 5.31ECh. 5 - Prob. 5.32ECh. 5 - Prob. 5.33ECh. 5 - Prob. 5.35ECh. 5 - Prob. 5.37ECh. 5 - Prob. 5.38ECh. 5 - Prob. 5.41ECh. 5 - Prob. 5.43ECh. 5 - Prob. 5.44ECh. 5 - Prob. 5.45ECh. 5 - Prob. 5.46ECh. 5 - Prob. 5.47ECh. 5 - Prob. 5.49ECh. 5 - Prob. 5.51ECh. 5 - Prob. 5.53ECh. 5 - Prob. 5.55ECh. 5 - Prob. 5.57ECh. 5 - Prob. 5.58ECh. 5 - Prob. 5.61ECh. 5 - Prob. 5.62E
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