The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given. Concept Introduction: Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture. Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

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Answer 1

Question

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

Answer 7

Chapter 5, Problem 5C.16E

(a)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water has to be given.

Concept Introduction:

Positive deviation from Raoult’s law is seen when the observed vapor pressure is greater than expected vapor pressure and it occurs when the A-B attractions are weaker than the average of the attractions in the pure components of the mixture.

Negative deviation from Raoult’s law occurs when the intermolecular forces between the dissimilar molecules are stronger than the average of the intermolecular forces in the pure substances.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5 - Prob. 5A.1AST Ch. 5 - Prob. 5A.1BST Ch. 5 - Prob. 5A.2AST Ch. 5 - Prob. 5A.2BST Ch. 5 - Prob. 5A.3AST Ch. 5 - Prob. 5A.3BST Ch. 5 - Prob. 5A.1E Ch. 5 - Prob. 5A.2E Ch. 5 - Prob. 5A.3E Ch. 5 - Prob. 5A.4E

Solution Summary: The author explains the type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water.

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).

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Chapter 5 Solutions

Solution Summary: The author explains the type of deviation (positive, negative or no deviation) expected for the mixture of hydrogen bromide and water.

Interpretation: The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given. Concept Introduction: Refer to part (a).

Interpretation: The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given. Concept Introduction: Refer to part (a).

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Chapter 5 Solutions

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of formic acid and benzene has to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The type of deviation (positive, negative or no deviation) expected for the mixture of cyclohexane and cyclopentane has to be given.

Concept Introduction:

Refer to part (a).