General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 5, Problem 5.72EP

(a)

Interpretation Introduction

Interpretation:

The bond formed between nitrogen and hydrogen has to be classified as nonpolar covalent, polar covalent or ionic.

Concept Introduction:

Close relationship between ionic and covalent bonding models becomes apparent if the bond polarity and electronegativity is considered.  Electronegativity is the measure of relative attractive for the shared pair of electrons in a bond.  Higher the electronegative value for an atom, the more it attracts the shared pair of electrons towards itself.

In Periodic table, when moving from left to right in a period, the electronegativity value increases.  While moving from top to bottom within group, the electronegativity value decreases.  Nonmetals have higher electronegativity values than metals.  Metals gives electrons and nonmetals accepts electrons.

Bond polarity is the degree of inequality in the electron pair sharing between two atoms in a chemical bond.  If the electrons are equally shared between two atoms then it is known as nonpolar covalent bond.  If the electrons are unequally shared between two atoms means then it is known as polar covalent bond.  The more electronegative atom pulls the shared pair of electrons towards itself resulting in fractional negative charge over it while the other atom gets a fractional positive charge.  The fractional negative charge is depicted by using the symbol δ and fractional positive charge is depicted using the symbol δ+.  The direction of polarity for a polar covalent bond can also be represented by an arrow in which a perpendicular line is passing through the tail.  The head is at the more electronegative atom in the bond.

The ionic and covalent bonds can be identified by using the electronegativity difference between the atoms that are bonded together.

  • Bonds that are formed between two similar electronegative atoms are known as nonpolar covalent bonds.  The electronegativity difference has to be 0.4 or less.
  • The bonds that have electronegativity difference greater than 0.4 and lesser than 1.5 are known as polar covalent bonds.
  • If the electronegativity difference is more than 2.0, then the bond is considered to be ionic.
  • If the electronegativity difference is between 1.5 to 2.0, then the bond can be ionic or covalent depending upon the type of atoms that is bonded.  If the bond is between a metal and nonmetal, then it is ionic and if it is between two nonmetals then it is polar covalent.

(b)

Interpretation Introduction

Interpretation:

The bond formed between nitrogen and carbon has to be classified as nonpolar covalent, polar covalent or ionic.

Concept Introduction:

Close relationship between ionic and covalent bonding models becomes apparent if the bond polarity and electronegativity is considered.  Electronegativity is the measure of relative attractive for the shared pair of electrons in a bond.  Higher the electronegative value for an atom, the more it attracts the shared pair of electrons towards itself.

In Periodic table, when moving from left to right in a period, the electronegativity value increases.  While moving from top to bottom within group, the electronegativity value decreases.  Nonmetals have higher electronegativity values than metals.  Metals gives electrons and nonmetals accepts electrons.

Bond polarity is the degree of inequality in the electron pair sharing between two atoms in a chemical bond.  If the electrons are equally shared between two atoms then it is known as nonpolar covalent bond.  If the electrons are unequally shared between two atoms means then it is known as polar covalent bond.  The more electronegative atom pulls the shared pair of electrons towards itself resulting in fractional negative charge over it while the other atom gets a fractional positive charge.  The fractional negative charge is depicted by using the symbol δ and fractional positive charge is depicted using the symbol δ+.  The direction of polarity for a polar covalent bond can also be represented by an arrow in which a perpendicular line is passing through the tail.  The head is at the more electronegative atom in the bond.

The ionic and covalent bonds can be identified by using the electronegativity difference between the atoms that are bonded together.

  • Bonds that are formed between two similar electronegative atoms are known as nonpolar covalent bonds.  The electronegativity difference has to be 0.4 or less.
  • The bonds that have electronegativity difference greater than 0.4 and lesser than 1.5 are known as polar covalent bonds.
  • If the electronegativity difference is more than 2.0, then the bond is considered to be ionic.
  • If the electronegativity difference is between 1.5 to 2.0, then the bond can be ionic or covalent depending upon the type of atoms that is bonded.  If the bond is between a metal and nonmetal, then it is ionic and if it is between two nonmetals then it is polar covalent.

(c)

Interpretation Introduction

Interpretation:

The bond formed between nitrogen and sulfur has to be classified as nonpolar covalent, polar covalent or ionic.

Concept Introduction:

Close relationship between ionic and covalent bonding models becomes apparent if the bond polarity and electronegativity is considered.  Electronegativity is the measure of relative attractive for the shared pair of electrons in a bond.  Higher the electronegative value for an atom, the more it attracts the shared pair of electrons towards itself.

In Periodic table, when moving from left to right in a period, the electronegativity value increases.  While moving from top to bottom within group, the electronegativity value decreases.  Nonmetals have higher electronegativity values than metals.  Metals gives electrons and nonmetals accepts electrons.

Bond polarity is the degree of inequality in the electron pair sharing between two atoms in a chemical bond.  If the electrons are equally shared between two atoms then it is known as nonpolar covalent bond.  If the electrons are unequally shared between two atoms means then it is known as polar covalent bond.  The more electronegative atom pulls the shared pair of electrons towards itself resulting in fractional negative charge over it while the other atom gets a fractional positive charge.  The fractional negative charge is depicted by using the symbol δ and fractional positive charge is depicted using the symbol δ+.  The direction of polarity for a polar covalent bond can also be represented by an arrow in which a perpendicular line is passing through the tail.  The head is at the more electronegative atom in the bond.

The ionic and covalent bonds can be identified by using the electronegativity difference between the atoms that are bonded together.

  • Bonds that are formed between two similar electronegative atoms are known as nonpolar covalent bonds.  The electronegativity difference has to be 0.4 or less.
  • The bonds that have electronegativity difference greater than 0.4 and lesser than 1.5 are known as polar covalent bonds.
  • If the electronegativity difference is more than 2.0, then the bond is considered to be ionic.
  • If the electronegativity difference is between 1.5 to 2.0, then the bond can be ionic or covalent depending upon the type of atoms that is bonded.  If the bond is between a metal and nonmetal, then it is ionic and if it is between two nonmetals then it is polar covalent.

(d)

Interpretation Introduction

Interpretation:

The bond formed between nitrogen and chlorine has to be classified as nonpolar covalent, polar covalent or ionic.

Concept Introduction:

Close relationship between ionic and covalent bonding models becomes apparent if the bond polarity and electronegativity is considered.  Electronegativity is the measure of relative attractive for the shared pair of electrons in a bond.  Higher the electronegative value for an atom, the more it attracts the shared pair of electrons towards itself.

In Periodic table, when moving from left to right in a period, the electronegativity value increases.  While moving from top to bottom within group, the electronegativity value decreases.  Nonmetals have higher electronegativity values than metals.  Metals gives electrons and nonmetals accepts electrons.

Bond polarity is the degree of inequality in the electron pair sharing between two atoms in a chemical bond.  If the electrons are equally shared between two atoms then it is known as nonpolar covalent bond.  If the electrons are unequally shared between two atoms means then it is known as polar covalent bond.  The more electronegative atom pulls the shared pair of electrons towards itself resulting in fractional negative charge over it while the other atom gets a fractional positive charge.  The fractional negative charge is depicted by using the symbol δ and fractional positive charge is depicted using the symbol δ+.  The direction of polarity for a polar covalent bond can also be represented by an arrow in which a perpendicular line is passing through the tail.  The head is at the more electronegative atom in the bond.

The ionic and covalent bonds can be identified by using the electronegativity difference between the atoms that are bonded together.

  • Bonds that are formed between two similar electronegative atoms are known as nonpolar covalent bonds.  The electronegativity difference has to be 0.4 or less.
  • The bonds that have electronegativity difference greater than 0.4 and lesser than 1.5 are known as polar covalent bonds.
  • If the electronegativity difference is more than 2.0, then the bond is considered to be ionic.
  • If the electronegativity difference is between 1.5 to 2.0, then the bond can be ionic or covalent depending upon the type of atoms that is bonded.  If the bond is between a metal and nonmetal, then it is ionic and if it is between two nonmetals then it is polar covalent.

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Chapter 5 Solutions

General, Organic, and Biological Chemistry

Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.3 - Prob. 4QQCh. 5.3 - Prob. 5QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Which of the following is an incorrect statement...Ch. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.6 - Prob. 3QQCh. 5.6 - Prob. 4QQCh. 5.6 - Prob. 5QQCh. 5.7 - Prob. 1QQCh. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - In VSEPR theory, an angular molecular geometry is...Ch. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.8 - Prob. 5QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.9 - Prob. 3QQCh. 5.9 - Prob. 4QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.10 - Prob. 3QQCh. 5.10 - As the difference in electronegativity between two...Ch. 5.10 - Prob. 5QQCh. 5.10 - Prob. 6QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.11 - Prob. 4QQCh. 5.11 - Prob. 5QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.12 - Prob. 5QQCh. 5.12 - Prob. 6QQCh. 5 - Contrast the types of elements involved in ionic...Ch. 5 - Contrast the mechanisms by which ionic and...Ch. 5 - Prob. 5.3EPCh. 5 - Prob. 5.4EPCh. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - The component elements for four binary molecular...Ch. 5 - The component elements for four binary molecular...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Identify the Period 3 nonmetal that would normally...Ch. 5 - How many valence electrons do atoms possess that...Ch. 5 - Prob. 5.22EPCh. 5 - What aspect of the following Lewis structure...Ch. 5 - What aspect of the following Lewis structure...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - How many electron dots should appear in the Lewis...Ch. 5 - Prob. 5.36EPCh. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - Prob. 5.45EPCh. 5 - What is the molecular geometry associated with...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Prob. 5.57EPCh. 5 - Specify both the VSEPR electron group geometry...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Using a periodic table, but not a table of...Ch. 5 - Using a periodic table, but not a table of...Ch. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Place + above the atom that is relatively positive...Ch. 5 - Place + above the atom that is relatively positive...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Fill in the blanks in each line of the following...Ch. 5 - Fill in the blanks in each line of the following...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Indicate whether each of the following...Ch. 5 - Prob. 5.78EPCh. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Indicate which molecule in each of the following...Ch. 5 - Indicate which molecule in each of the following...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Prob. 5.89EPCh. 5 - Indicate whether or not each of the following...Ch. 5 - Prob. 5.91EPCh. 5 - Name the following binary molecular compounds? a....Ch. 5 - Prob. 5.93EPCh. 5 - Prob. 5.94EPCh. 5 - Prob. 5.95EPCh. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Write chemical formulas for the following binary...Ch. 5 - Write chemical formulas for the following binary...Ch. 5 - Prob. 5.101EPCh. 5 - Prob. 5.102EPCh. 5 - The compound whose molecles contain one atom of C...Ch. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - The correct name for the compound K2SO4 is not...Ch. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EP
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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY