General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 5, Problem 5.45EP

(a)

Interpretation Introduction

Interpretation:

With four bonding groups and zero nonbonding groups about the central atom, the molecular geometry that is associated has to be given.

Concept Introduction:

Information about the number of bonds and types of bonds can be obtained from Lewis structure but the molecular geometry cannot be obtained.  Three dimensional arrangement of atoms in a molecule can be given by molecular geometry.  Physical and chemical properties are determined by the molecular geometry of the molecule.

Using VSEPR theory and Lewis structure, the molecular geometry of the molecule that contain less number of atoms can be predicted.  VSEPR theory uses the information from Lewis structure of the molecule to predict the molecular geometry of the molecule.  Main concept of VSEPR theory is that electron pairs that are present in the valence shell adopt arrangement in a way that minimize the repulsion between like charges.

If the central atom contains two electron pairs, then it has to be far apart means, it has to be on opposite side of the nucleus.  This means the angle has to be 180° between them.  This type of arrangement for electron pair result in linear.

If the central atom contains three electron pairs, then it has to be far apart means, it has to be on corner of a triangle.  This means the angle has to be 120° between them.  This type of arrangement for electron pair result in trigonal planar.

If the central atom contains four electron pairs, then it has to be far apart means, it has to be in a tetrahedral arrangement.  This means the angle has to be 109° between them.  This type of arrangement for electron pair result in tetrahedral.

The collection of valence electron that is present in localized region about central atom in a molecule is known as VSEPR electron group.  This may contain two electrons, four electrons, or six electrons.  The electron group that contain four and six electrons repel each other.

Tetrahedral VSEPR electron group:

The four electron pairs can be of three VSEPR electron groups.  They are 4 bonding electron groups, 3 bonding and 1 nonbonding electron groups, and 2 bonding and 2 nonbonding electron groups.  The molecular geometry that is associated with 4 bonding electron groups is tetrahedral.  The molecular geometry that is associated with 3 bonding and 1 nonbonding electron groups is trigonal pyramidal.  The molecular geometry that is associated with 2 bonding and 2 nonbonding electron groups is angular.

Trigonal planar VSEPR electron group:

The three electron pairs can be of two VSEPR electron groups.  They are 3 bonding electron groups, and 2 bonding and 1 nonbonding electron groups.  The molecular geometry that is associated with 3 bonding electron groups is trigonal planar.  The molecular geometry that is associated with 2 bonding and 1 nonbonding electron groups is angular.

Linear VSEPR electron group:

The two electron pairs can be of only one VSEPR electron groups.  It is only 2 bonding electron groups and the geometry associated with it is linear geometry.

(b)

Interpretation Introduction

Interpretation:

With two bonding groups and two nonbonding groups about the central atom, the molecular geometry that is associated has to be given.

Concept Introduction:

Information about the number of bonds and types of bonds can be obtained from Lewis structure but the molecular geometry cannot be obtained.  Three dimensional arrangement of atoms in a molecule can be given by molecular geometry.  Physical and chemical properties are determined by the molecular geometry of the molecule.

Using VSEPR theory and Lewis structure, the molecular geometry of the molecule that contain less number of atoms can be predicted.  VSEPR theory uses the information from Lewis structure of the molecule to predict the molecular geometry of the molecule.  Main concept of VSEPR theory is that electron pairs that are present in the valence shell adopt arrangement in a way that minimize the repulsion between like charges.

If the central atom contains two electron pairs, then it has to be far apart means, it has to be on opposite side of the nucleus.  This means the angle has to be 180° between them.  This type of arrangement for electron pair result in linear.

If the central atom contains three electron pairs, then it has to be far apart means, it has to be on corner of a triangle.  This means the angle has to be 120° between them.  This type of arrangement for electron pair result in trigonal planar.

If the central atom contains four electron pairs, then it has to be far apart means, it has to be in a tetrahedral arrangement.  This means the angle has to be 109° between them.  This type of arrangement for electron pair result in tetrahedral.

The collection of valence electron that is present in localized region about central atom in a molecule is known as VSEPR electron group.  This may contain two electrons, four electrons, or six electrons.  The electron group that contain four and six electrons repel each other.

Tetrahedral VSEPR electron group:

The four electron pairs can be of three VSEPR electron groups.  They are 4 bonding electron groups, 3 bonding and 1 nonbonding electron groups, and 2 bonding and 2 nonbonding electron groups.  The molecular geometry that is associated with 4 bonding electron groups is tetrahedral.  The molecular geometry that is associated with 3 bonding and 1 nonbonding electron groups is trigonal pyramidal.  The molecular geometry that is associated with 2 bonding and 2 nonbonding electron groups is angular.

Trigonal planar VSEPR electron group:

The three electron pairs can be of two VSEPR electron groups.  They are 3 bonding electron groups, and 2 bonding and 1 nonbonding electron groups.  The molecular geometry that is associated with 3 bonding electron groups is trigonal planar.  The molecular geometry that is associated with 2 bonding and 1 nonbonding electron groups is angular.

Linear VSEPR electron group:

The two electron pairs can be of only one VSEPR electron groups.  It is only 2 bonding electron groups and the geometry associated with it is linear geometry.

(c)

Interpretation Introduction

Interpretation:

With three bonding groups and zero nonbonding groups about the central atom, the molecular geometry that is associated has to be given.

Concept Introduction:

Information about the number of bonds and types of bonds can be obtained from Lewis structure but the molecular geometry cannot be obtained.  Three dimensional arrangement of atoms in a molecule can be given by molecular geometry.  Physical and chemical properties are determined by the molecular geometry of the molecule.

Using VSEPR theory and Lewis structure, the molecular geometry of the molecule that contain less number of atoms can be predicted.  VSEPR theory uses the information from Lewis structure of the molecule to predict the molecular geometry of the molecule.  Main concept of VSEPR theory is that electron pairs that are present in the valence shell adopt arrangement in a way that minimize the repulsion between like charges.

If the central atom contains two electron pairs, then it has to be far apart means, it has to be on opposite side of the nucleus.  This means the angle has to be 180° between them.  This type of arrangement for electron pair result in linear.

If the central atom contains three electron pairs, then it has to be far apart means, it has to be on corner of a triangle.  This means the angle has to be 120° between them.  This type of arrangement for electron pair result in trigonal planar.

If the central atom contains four electron pairs, then it has to be far apart means, it has to be in a tetrahedral arrangement.  This means the angle has to be 109° between them.  This type of arrangement for electron pair result in tetrahedral.

The collection of valence electron that is present in localized region about central atom in a molecule is known as VSEPR electron group.  This may contain two electrons, four electrons, or six electrons.  The electron group that contain four and six electrons repel each other.

Tetrahedral VSEPR electron group:

The four electron pairs can be of three VSEPR electron groups.  They are 4 bonding electron groups, 3 bonding and 1 nonbonding electron groups, and 2 bonding and 2 nonbonding electron groups.  The molecular geometry that is associated with 4 bonding electron groups is tetrahedral.  The molecular geometry that is associated with 3 bonding and 1 nonbonding electron groups is trigonal pyramidal.  The molecular geometry that is associated with 2 bonding and 2 nonbonding electron groups is angular.

Trigonal planar VSEPR electron group:

The three electron pairs can be of two VSEPR electron groups.  They are 3 bonding electron groups, and 2 bonding and 1 nonbonding electron groups.  The molecular geometry that is associated with 3 bonding electron groups is trigonal planar.  The molecular geometry that is associated with 2 bonding and 1 nonbonding electron groups is angular.

Linear VSEPR electron group:

The two electron pairs can be of only one VSEPR electron groups.  It is only 2 bonding electron groups and the geometry associated with it is linear geometry.

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Students have asked these similar questions
compounds have a dipole moment if they are  a. diatomic molecules made up of atoms of the same element  b. nonpolar covalent molecules  c. polar covalent molecules  d. polyatomic molecules made up of atoms of the same element
Step 1 – Write the Lewis structure from the molecular formula.Step 2 – Assign an electron-group arrangement by counting all electron groups (bonding plus nonbonding) around the central atom (or around each centralatom, if more than one central atom in structure).Step 3 – Predict the ideal bond angle from the electron-group arrangement and the effect of any deviation caused by lone pairs or double bonds.Step 4 – Name the molecular shape by counting bonding groups and nonbonding groups separately.Step 5 – Predict whether the molecule is polar or nonpolarStep 6 – Describe the hybridization around the central atom and identify the total number of σ and π bonds in the structure
A. Fluoromethane B. Methanol C. Chloromethane D. Water 1. Which molecule has the highest dipole moment? 2. Which molecule has the greatest bond angle relative to the electronegative atom? 3. Which molecule has the most optimal bond angle? 4. Which molecule is the most polar? 5. Which molecule contains the most electronegative atom?

Chapter 5 Solutions

General, Organic, and Biological Chemistry

Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.3 - Prob. 4QQCh. 5.3 - Prob. 5QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Which of the following is an incorrect statement...Ch. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.6 - Prob. 3QQCh. 5.6 - Prob. 4QQCh. 5.6 - Prob. 5QQCh. 5.7 - Prob. 1QQCh. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - In VSEPR theory, an angular molecular geometry is...Ch. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.8 - Prob. 5QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.9 - Prob. 3QQCh. 5.9 - Prob. 4QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.10 - Prob. 3QQCh. 5.10 - As the difference in electronegativity between two...Ch. 5.10 - Prob. 5QQCh. 5.10 - Prob. 6QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.11 - Prob. 4QQCh. 5.11 - Prob. 5QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.12 - Prob. 5QQCh. 5.12 - Prob. 6QQCh. 5 - Contrast the types of elements involved in ionic...Ch. 5 - Contrast the mechanisms by which ionic and...Ch. 5 - Prob. 5.3EPCh. 5 - Prob. 5.4EPCh. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - The component elements for four binary molecular...Ch. 5 - The component elements for four binary molecular...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Identify the Period 3 nonmetal that would normally...Ch. 5 - How many valence electrons do atoms possess that...Ch. 5 - Prob. 5.22EPCh. 5 - What aspect of the following Lewis structure...Ch. 5 - What aspect of the following Lewis structure...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - How many electron dots should appear in the Lewis...Ch. 5 - Prob. 5.36EPCh. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - Prob. 5.45EPCh. 5 - What is the molecular geometry associated with...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Prob. 5.57EPCh. 5 - Specify both the VSEPR electron group geometry...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Using a periodic table, but not a table of...Ch. 5 - Using a periodic table, but not a table of...Ch. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Place + above the atom that is relatively positive...Ch. 5 - Place + above the atom that is relatively positive...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Fill in the blanks in each line of the following...Ch. 5 - Fill in the blanks in each line of the following...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Indicate whether each of the following...Ch. 5 - Prob. 5.78EPCh. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Indicate which molecule in each of the following...Ch. 5 - Indicate which molecule in each of the following...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Prob. 5.89EPCh. 5 - Indicate whether or not each of the following...Ch. 5 - Prob. 5.91EPCh. 5 - Name the following binary molecular compounds? a....Ch. 5 - Prob. 5.93EPCh. 5 - Prob. 5.94EPCh. 5 - Prob. 5.95EPCh. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Write chemical formulas for the following binary...Ch. 5 - Write chemical formulas for the following binary...Ch. 5 - Prob. 5.101EPCh. 5 - Prob. 5.102EPCh. 5 - The compound whose molecles contain one atom of C...Ch. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - The correct name for the compound K2SO4 is not...Ch. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EP
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