Products formed for the reaction have to be predicted. The given reaction is shown as, Concept Introduction: Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors. Strong deactivators: They are very strong electron withdrawing groups. Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group. Weak deactivators: It consists of halogens. Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing. Strong activators: It contains a lone pair next to the aromatic ring. Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well. Weak activators: It consists of alkyl groups. Halogens are deactivators that are ortho-para directing. Rules to identify the group that dominates the directing effects: Ortho-para directors will always dominate meta directors. Strong activators will always dominate weak activators Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Question

Want to see the full answer?

Answer 1

Question

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI OH woཡི།༠w Br H مه D CI ပ။ Br H, Br Br H₂N OMe R IN Ill N S H CI Br CI CI D OH H 1/111

Draw the two products of the reaction. H₂C. CH₂ H :0: CH3 CH₂ +1

Show work. Don't give Ai generated solution

Answer 2

Question

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Answer 6

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Answer 7

Chapter 4.7, Problem 4.79P

Interpretation Introduction

Interpretation:

Products formed for the reaction have to be predicted. The given reaction is shown as,

Concept Introduction:

Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.

Strong deactivators: They are very strong electron withdrawing groups.

Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.

Weak deactivators: It consists of halogens.

Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.

Strong activators: It contains a lone pair next to the aromatic ring.

Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.

Weak activators: It consists of alkyl groups.

Halogens are deactivators that are ortho-para directing.

Rules to identify the group that dominates the directing effects:

Ortho-para directors will always dominate meta directors.

Strong activators will always dominate weak activators

Friedel-Crafts Acylation: This Lewis acid-catalyzed electrophilic aromatic substitution is the reaction between arenes and acyl chlorides or anhydrides for the synthesis of monoacylated compound. The products are deactivated, as well as do not undergo a second substitution.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 4.1 - Consider the following reaction, in which an...Ch. 4.1 - Prob. 4.3P Ch. 4.1 - Aromatic rings will also undergo iodination when...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.3 - Prob. 4.10P Ch. 4.3 - Prob. 4.11P Ch. 4.3 - Prob. 4.12P Ch. 4.3 - Prob. 4.13P

Solution Summary: The author describes Friedel-Crafts Acylation as a Lewis acid-catalyzed electrophilic aromatic substitution reaction between arenes and acyl chlorides.

Want to see the full answer?

Chapter 4 Solutions