ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
4th Edition
ISBN: 9781119761068
Author: Klein
Publisher: WILEY
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Question
Chapter 4.9, Problem 4.101P
Interpretation Introduction
Interpretation:
An efficient synthesis for the given transformation has to be predicted. The given reaction is shown as,
Concept Introduction:
Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.
Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.
Halogens are deactivators that are ortho-para directing.
Bromination: A reaction in which a bromine atom is introduced to the compound.
Nitration: In nitration reaction, one nitro group
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Students have asked these similar questions
Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic.
НОН НЬ
OHd
Онс
Can the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left?
?
starting
material
target
If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area.
Be sure you follow the standard ALEKS rules for submitting syntheses.
+ More...
Note for advanced students: you may assume that you are using a large excess of benzene as your starting material.
C
:0
T
Add/Remove step
G
The following equations represent the formation of compound MX. What is the AH for the
electron affinity of X (g)?
X₂ (g) → 2X (g)
M (s) → M (g)
M (g)
M (g) + e-
AH = 60 kJ/mol
AH = 22 kJ/mol
X (g) + e-X (g)
M* (g) +X (g) → MX (s)
AH = 118 kJ/mol
AH = ?
AH = -190 kJ/mol
AH = -100 kJ/mol
a)
-80 kJ
b)
-30 kJ
c)
-20 kJ
d)
20 kJ
e)
156 kJ
Chapter 4 Solutions
ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
Ch. 4.1 - Consider the following reaction, in which an...Ch. 4.1 - Prob. 4.3PCh. 4.1 - Aromatic rings will also undergo iodination when...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.3 - Prob. 4.10PCh. 4.3 - Prob. 4.11PCh. 4.3 - Prob. 4.12PCh. 4.3 - Prob. 4.13P
Ch. 4.3 - Prob. 4.14PCh. 4.3 - Predict the products of the following reaction.Ch. 4.3 - Prob. 4.16PCh. 4.3 - Prob. 4.17PCh. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - Prob. 4.27PCh. 4.4 - Prob. 4.28PCh. 4.4 - And now, for a challenging problem, try to draw...Ch. 4.6 - Prob. 4.31PCh. 4.6 - Prob. 4.32PCh. 4.6 - Prob. 4.33PCh. 4.6 - Prob. 4.34PCh. 4.6 - Prob. 4.35PCh. 4.6 - Prob. 4.36PCh. 4.6 - Prob. 4.37PCh. 4.6 - Prob. 4.40PCh. 4.6 - Prob. 4.41PCh. 4.6 - Predict the products for each of the following...Ch. 4.6 - Predict the products for each of the following...Ch. 4.6 - Predict the products for each of the following...Ch. 4.6 - Predict the products for each of the following...Ch. 4.6 - Prob. 4.47PCh. 4.6 - Prob. 4.48PCh. 4.6 - Prob. 4.49PCh. 4.6 - Prob. 4.50PCh. 4.6 - Prob. 4.51PCh. 4.6 - Prob. 4.52PCh. 4.6 - Prob. 4.53PCh. 4.6 - Prob. 4.54PCh. 4.6 - Prob. 4.55PCh. 4.6 - Prob. 4.56PCh. 4.7 - Prob. 4.58PCh. 4.7 - Prob. 4.59PCh. 4.7 - Prob. 4.60PCh. 4.7 - Prob. 4.61PCh. 4.7 - Prob. 4.62PCh. 4.7 - Prob. 4.63PCh. 4.7 - Prob. 4.64PCh. 4.7 - Prob. 4.65PCh. 4.7 - Prob. 4.66PCh. 4.7 - Prob. 4.67PCh. 4.7 - Can you explain why the following group is a...Ch. 4.7 - Prob. 4.70PCh. 4.7 - Prob. 4.71PCh. 4.7 - Prob. 4.72PCh. 4.7 - Prob. 4.73PCh. 4.7 - Prob. 4.74PCh. 4.7 - Prob. 4.76PCh. 4.7 - Prob. 4.77PCh. 4.7 - Prob. 4.78PCh. 4.7 - Prob. 4.79PCh. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Prob. 4.87PCh. 4.8 - Prob. 4.88PCh. 4.8 - Prob. 4.89PCh. 4.8 - Prob. 4.90PCh. 4.8 - Prob. 4.91PCh. 4.8 - Prob. 4.92PCh. 4.9 - Prob. 4.94PCh. 4.9 - Prob. 4.95PCh. 4.9 - Prob. 4.96PCh. 4.9 - Prob. 4.97PCh. 4.9 - Prob. 4.98PCh. 4.9 - Prob. 4.99PCh. 4.9 - Prob. 4.100PCh. 4.9 - Prob. 4.101PCh. 4.9 - Prob. 4.102P
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