Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 4, Problem 4.61P
Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other.
a. 
and
e. 
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b. 
and
f. 
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c. 
and
g. 
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d. 
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h. 
and 
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Determine if each compound is a. constitutional isomers b. enantionmers c. diastereomers d. the same molecule
1. Name each compound and determine the relationship between the pairs of compounds.
O
a. Name:
b. Name:
N
C. Relationship between structures above: Conformational isomer or Structural isomer
2. Name:
3. Is the following structure the cis stereoisomer or the trans stereoisomer?
1. Name each compound and determine the relationship between the pairs of compounds.
a. Name:
b. Name:
Relationship between structures above: Conformational isomer or Structural isomer
2. Name:
3. Is the following structure the cis stereoisomer or the trans stereoisomer?
Chapter 4 Solutions
Organic Chemistry-Package(Custom)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - (a) Classify the carbon atoms in each compound as...Ch. 4 - Problem 3.3 Classify a carbon atom by the number...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Give the IUPAC name for each compound. a. c. b. ...Ch. 4 - Give the IUPAC name for each compound. a....
Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- The following pair of molecules is best described as: Select one: a. structural isomers O b. configurational isomers O c. conformations of the same molecule d. not a pair of isomers nor conformations of the same moleculearrow_forward6. Which of the following is not a constitutional isomer of the others? A. B. C. LOH etsarn D. -OHarrow_forwardHow are the ball-and-stick models A and B related to each other? Do they represent constitutional isomers or identical molecules?arrow_forward
- Determine whether each compound exhibits optical isomerism. a. CCl, b. CH;-CH2-CH-CH;-CH,-CH2-CH, CH3 H c. CH,-C-CI NH2 d. CH,CHCICH,arrow_forwardDetermine whether each compound exhibits optical isomerism. a. CCI4 b. CH3-CH2-CH-CH;-CH;-CH;-CH3 c. H CH3-C-CI NH2 d. CH,CHCICH,arrow_forwardClassify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other.arrow_forward
- 1. Give the IUPAC name of the following compoundarrow_forwarda. 4.59 Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other. and H- Дон -CH3 CH3 H b. and d. CH3CH2 H CH2CH3 and CH3CH2 CH3 H and CH3 H CH2CH3 Harrow_forward9. Identify the relationship between the following pair of molecules? CI A. Same molecule. B. constitutional isomers. C. enantiomers. D. diastereomers E. different compounds (not isomers) and 10. Identify the relationship between the following pair of molecules? OH HO and HO HO A. Same molecule. B. constitutional isomers. C. enantiomers. D. diastereomers E. not isomers (different compounds)arrow_forward
- Hydrocarbons with only single covalent bond are known as... Select one: O a. alkanes O b. allylenes O C. alkynes O d. alkenesarrow_forwardDraw the structure of all compounds that t the following descriptions.a. ve constitutional isomers having the molecular formula C4H8b. nine constitutional isomers having the molecular formula C7H16c. twelve constitutional isomers having the molecular formula C6H12 and containing one ringarrow_forwardName each compound and indicate the conformation around the σ bond that joins the two double bonds.arrow_forward
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