Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 4, Problem 4.40P
Give the structure and IUPAC name for each of the nine isomers having molecular formula
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What alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2?
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NN
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CH3-CH₂-C-N-CH₂-CH3
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CH₂-C-N-CH₂-CH₂-CH₂,
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diethylamine
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Chapter 4 Solutions
Organic Chemistry-Package(Custom)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - (a) Classify the carbon atoms in each compound as...Ch. 4 - Problem 3.3 Classify a carbon atom by the number...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Give the IUPAC name for each compound. a. c. b. ...Ch. 4 - Give the IUPAC name for each compound. a....
Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- Give the IUPAC name of the following alcohols and phenols.arrow_forwardGive the IUPAC name for each of the fi ve constitutional isomers of molecular formula C 6H 14 in Problem 12.40.arrow_forwardWrite structural formulas for all ketones with the molecular formula C6H12O and give each its IUPAC name. Which of these ketones are chiral?arrow_forward
- draw the structure of two costitution isomers with the molecular formula of C4H10. Give the IUPAC name of each isomerarrow_forwardCH3 CH2 CH3 CH CH2 Provide the IUPAC name of the compound. Parent name: Substituents: Locants: IUPAC Name:arrow_forwardComplete the table by drawing the bond line structure, number of carbons in the parent chain, and its respective (systematic) IUPAC name.arrow_forward
- Draw three constitutional isomers having molecular formula C 7H 14 that contain a fi ve-membered ring and two CH 3 groups bonded to the ring. Give the IUPAC name for each isomerarrow_forwardGive the structural formula (condensed or skeletal) of the given IUPAC names of saturated hydrocarbons. 1) 2-methyl-3-oxohept-4-enoic acid 2) 4-chloro-2-oxohexanoyl chloride 3) 4-nitro-4-propoxybut-1-ene 4) 1-hydroxyhex-5-yn-2-one 5) 1-methylpropyl 3-amino-3-(1-methylpropoxy)propanoate 6) 1-ethoxy-3-mercaptohexane-2-thionearrow_forwardBased on naming branched alkyl substituents, and draw all possible alkyl groups having the formula C5H11–. Give the IUPAC names for the eight compounds of molecular formula C10H20that contain a cyclopentane ring with each of these alkyl groups as a substituent.arrow_forward
- Give the IUPAC NAME of the following compound: Vour ancworarrow_forwardPolyisobutylene, a synthetic high molecular weight alkane with many properties similar to polyethylene (Section 11.5A), is the principal component of Elastol, a product used to clean up oil spills. Elastol dissolves oil to form a thick mat that can be skimmed or suctioned from the surface. Explain why oil dissolves in Elastol.arrow_forwardDraw a cyclic ether with molecular formula C5H10Oarrow_forward
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