Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 4, Problem 4.36P
For each
hydrogen atom as
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For each alkane:
(a) classify each carbon atom as 1°, 2°, 3°, or 4°;
(b) classify each hydrogen atom as 1°, 2°, or 3°.
(a) Enter the IUPAC name for this alcohol:
CH,CH,CHCH,
ОН
Classify it as a primary, secondary, or tertiary alcohol:
(b) Enter the IUPAC name for this alcohol:
CH,CHCH,CH,CHOH
CH,
ČH,
Classify it as a primary, secondary, or tertiary alcohol:
1: Give at least five (5) uses of Alcohol and Phenol
Name
Functional Group
R-OH
Alcohols
LOH
Phenols
Based on the illustration above. What is the difference between
alcohol and phenol?
Can Phenol react with alcohol?
Chapter 4 Solutions
Organic Chemistry-Package(Custom)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - (a) Classify the carbon atoms in each compound as...Ch. 4 - Problem 3.3 Classify a carbon atom by the number...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Give the IUPAC name for each compound. a. c. b. ...Ch. 4 - Give the IUPAC name for each compound. a....
Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- Indicate whether each statement is true or false. (a) Alkanesdo not contain any carbon–carbon multiple bonds.(b) Cyclobutane contains a four-membered ring. (c) Alkenescontain carbon–carbon triple bonds. (d) Alkynes containcarbon–carbon double bonds. (e) Pentane is a saturatedhydrocarbon but 1-pentene is an unsaturated hydrocarbon.(f) Cyclohexane is an aromatic hydrocarbon. (g) The methylgroup contains one less hydrogen atom than methane.arrow_forwardnt Answer true or false. (a) The functional group of an alcohol is the -OH (hydroxyl) group. 1 (b) The parent name of an alcohol is the name of the longest carbon chain that contains the -OH group. (c) 1°, 2°, and 3° refer to the number of carbon groups bonded to the carbon bearing the -OH group. (d) In the IUPAC system, the presence of three -OH groups is shown by the ending -triol. (e) Glycols are diols where the two hydroxyl groups are bonded to two adjacent carbons. (f) Because of the presence of an -OH group, all alcohols are polar compounds. (g) The boiling points of alcohols decrease with increasing molecular weight. Q $ 0 % [References] L MacBook Pro Cengage Learning Cengage Technical Support Œ (arrow_forwardName these aldehydes:arrow_forward
- OH Amide H-C-0 H 100 (C) (a)arrow_forward2. Classify each compound as an alcohol, aldehyde, sugar, ketone, methyl ketone, or hydrocarbon (there should only be one of each type of compound). Hexane Ethanol Benzaldehyde Cyclohexanone Acetone (Propanone) Glucose emplearrow_forward1: Give at least five (5) uses of Etherin medicine. CH3 CH,-0-C-CH, CH, common name: methyl-t-butyl ether (MTBE) IUPAC name: 2-methoxy-2-methylpropane diphenyl ether or phenyl ether phenoxybenzene Analyze the given ether. Then describe the structural formula.arrow_forward
- Give the IUPAC name of each of the following compounds. (a) CH3CH2CH2-----OH (b) CH3---CH2---C----H || O (c) CH3CH2CH2CH2---C--CH3 || O (d) CH3---CH2----CH2----C---OH || Oarrow_forwarda) Draw the four isomers of C5H12O that can be oxidized to an aldehyde. (b) Draw the three isomers of C5H12O that can be oxidized to a ketone. (c) Draw the isomers of C5H12O that cannot be easily oxidized to an aldehyde or ketone. (d) Name any isomer that is an alcohol.arrow_forwardCyclopentane has a higher boiling point than pentane even though both compounds have the same number of carbons (49 °C vs. 36 °C). Can you suggest a reason for this phenomenon?arrow_forward
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