Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 32, Problem 32.13QAP
Interpretation Introduction

Interpretation:

The conditions in which the second term of following equation is ignored are to be determined.

mx=RtRm×mmmt

Concept introduction:

Isotope dilution method is a method in which the quantity of chemical substance is determined. In this method istopically enriched known substance added to the analyzed sample.

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An oxygen (O,) molecule is adsorbed on a patch of surface (see sketch at right). This patch is known to contain 784 adsorption sites. The (0,) molecule has enough energy to move from site to site, so it could be on any one of them. Suppose additional surface becomes exposed, so that 1089 adsorption sites are now available for the molecule. Calculate the change in entropy. One way an 0, molecule could be adsorbed on a patch of Round your answer to 3 significant digits, and be sure it has the correct unit symbol. surface with 16 sites. x10 ?
An oxygen (0,) molecule is adsorbed on a patch of surface (see sketch at right). This patch is known to contain 529 adsorption sites. The (0,) molecule has enough energy to move from site to site, so it could be on any one of them. Suppose part of the surface becomes inaccessible, so that only 196 adsorption sites are now available for the molecule. Calculate the change in entropy. One way an O, molecule could Round your answer to 3 significant digits, and be sure it has the correct unit symbol. be adsorbed on a patch of surface with 16 sites.
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