Concept explainers
Interpretation:
The fraction of radionuclide which will remain after 1 day, 2days, 3 days and 4 days is to be determined. The samples are iron-59 (44.51 days), titanium-45 (3.078h), calcium-47(4.536days) and phosphorus-33 (25.3 days).
Concept introduction:
According to first order of kinetics:
Here, N and No are final and initial concentrations,
Here,
Answer to Problem 32.3QAP
The fraction of radionuclide which will remain after 1 day, 2 days, 3 days and 4 days is −
Radioactive element | t hr |
24 |
t hr |
48 |
t hr |
72 |
t hr |
96 |
Iron-59 | 0.0156 | 0.98455 | -0.0311 | 0.9693343 | -0.0467 | 0.95436 | -0.0622914 | 0.93961 |
Titanium-45 | -5.4047 | 0.0045 | -10.809 | -16.214 | -21.618626 | |||
Calcium-47 | -0.1528 | 0.085829 | -0.3056 | -0.4584 | 0.63228 | -0.6112409 | 0.54268 | |
Phosphorous-33 | -0.0274 | 0.97297 | -0.0548 | 0.9466799 | -0.0822 | 0.9211 | -0.1095885 | 0.8962 |
Explanation of Solution
The formula for the half time of sample can be calculated by using the following formula-
The formula for the fraction of sample and time can be calculated by using the following formula-
Where,
N and N0 = number of radioactive nuclei
The half- time of the radioactive elements are given as-
Iron-59 = 44.51 days
Titanium-45 = 3.078h
Calcium-47= 4.536days
Phosphorus-33 = 25.3 days
By using the above formulas following data will be calculated-
Radioactive elements | ||||||
Iron-59 | 44.51 days | 1068.24 hr | 0.00065 | |||
Titanium-45 | 3.078 hr | 3.078 hr | 0.22519 | |||
Calcium-47 | 4.536 days | 108.864 hr | 0.00637 | |||
Phosphorous-33 | 25.3 days | 607.2 hr | 0.00114 | |||
For t=24 hr | t hr | 24 | t= 48 hr | t hr | 48 | |
Iron-59 | 0.0156 | 0.98455 | -0.0311 | 0.9693343 | ||
Titanium-45 | -5.4047 | 0.0045 | -10.809 | |||
Calcium-47 | -0.1528 | 0.085829 | -0.3056 | 0.7366662 | ||
Phosphorous-33 | -0.0274 | 0.97297 | -0.0548 | 0.9466799 | ||
t =72 hr | t hr | 72 | t = 96 hr | t hr | 96 | |
-0.0467 | 0.95436 | -0.0622914 | 0.93961 | |||
-16.214 | -21.618626 | |||||
-0.4584 | 0.63228 | -0.6112409 | 0.54268 | |||
-0.0822 | 0.9211 | -0.1095885 | 0.8962 |
Spreadsheet documentation of the above table is −
The fraction remained after 1 day, 2 days, 3 days and 4 days is −
Radioactive element | t hr |
24 |
t hr |
48 |
t hr |
72 |
t hr |
96 |
Iron-59 | 0.0156 | 0.98455 | -0.0311 | 0.9693343 | -0.0467 | 0.95436 | -0.0622914 | 0.93961 |
Titanium-45 | -5.4047 | 0.0045 | -10.809 | -16.214 | -21.618626 | |||
Calcium-47 | -0.1528 | 0.085829 | -0.3056 | -0.4584 | 0.63228 | -0.6112409 | 0.54268 | |
Phosphorous-33 | -0.0274 | 0.97297 | -0.0548 | 0.9466799 | -0.0822 | 0.9211 | -0.1095885 | 0.8962 |
The formula for the fraction of sample and half time of sample is used for the calculation of the fraction of radionuclide which will remain after 1 day, 2days, 3 days and 4 days for radioactive elements iron-59, titanium-45, calcium- 47, and phosphorous-33. Therefore,
Radioactive element | t hr
|
24
|
t hr
|
48
|
t hr
|
72
|
t hr
|
96
|
Iron-59 | 0.0156 | 0.98455 | -0.0311 | 0.9693343 | -0.0467 | 0.95436 | -0.0622914 | 0.93961 |
Titanium-45 | -5.4047 | 0.0045 | -10.809 | -16.214 | -21.618626 | |||
Calcium-47 | -0.1528 | 0.085829 | -0.3056 | -0.4584 | 0.63228 | -0.6112409 | 0.54268 | |
Phosphorous-33 | -0.0274 | 0.97297 | -0.0548 | 0.9466799 | -0.0822 | 0.9211 | -0.1095885 | 0.8962 |
Want to see more full solutions like this?
Chapter 32 Solutions
Principles of Instrumental Analysis
- 1.) Using the graph below (including the line equation of y = -1.823x - 0.0162) What is the numerical value for the slope shown? 2.) What are the Unit(s) associated with the slope of the line shown? for we all remember that numerical data always has units. 3.) What would be a good title for this graph and explain your choice. 0.00 0.0 02 0.4 10.6 08 10 12 -0.20 -0.40 -0.60 -0.80 Temp, freezing, in degrees Celcius 5-1.00 -1.20 -1.40 -1:60 y=-1.823x-0.0162 -180 -2.00 Concentration of Sucrose (m)arrow_forwardDon't used Ai solutionarrow_forwardIdentify the Functional Groups (FG) in the following molecules. Classify C atoms as tertiary, 30, or quaternary 40. Identify secondary 20 and tertiary, 30 hydrogen atoms. Please provide steps to undertand each labeling. Please label in the image, so it fits explanation. I am still very unsure I undertand this.arrow_forward
- Several square planar complexes are known for Gold (III) ions but not for Silver (III) why?arrow_forwardAiter running various experiments, you determine that the mechanism for the following reaction is bimolecular. CI Using this information, draw the correct mechanism in the space below. X Explanation Check C Cl OH + CI Add/Remove step Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Carrow_forwardComplete the reaction in the fewest number of steps as possible, Draw all intermediates (In the same form as the picture provided) and provide all reagents.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning