Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 32, Problem 32.2QAP
Interpretation Introduction

Interpretation:

The half-life of ß emitter that is potassium -42 is 12.36h. The fraction of radionuclide is to be determined from the sample of 1,10,20,30,40,50,60,70,80,90 and 100h.The graph is to be plotted between the fraction remaining and the time which is required for the fraction to fall 1% is to be determined.

Concept introduction:

According to first order of kinetics:

ln(NN0)=λt

Here, N and No are final and initial concentrations, λ is decay constant and t is time.

t1/2(halftime)=ln2λ

Here, t1/2 is half-life time.

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