Draw the structure of pre- polymer and show the cross-linking effect of addition of pre-polymer to triamine. Concept introduction: The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl) .

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

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What is the structural requirement for a substance to react with ammoniacal AgNO3? Why would acetylene react with Tollen's reagent but not cyclohexane or cyclohexene?

Ph3P-CHCH3 H₂C H3C Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called the Wittig reaction. In the reaction, a triphenylphosphorine ylide, also called a phosphorane, adds to an aldehyde/ketone to give a four-membered cyclic intermediate called an oxaphosphetane. The oxaphosphetane is not isolated but instead spontaneously decomposes to release triphenylphosphine oxide and an alkene. CH3 00 + The ylide is formed by reaction of triphenylphosphine, a good nucleophile, with a primary alkyl halide in an SN2 reaction, followed by deprotonation of the carbon with a strong base, such as butyllithium. The carbonyl carbon and the carbon originally bonded to the halogen become the two carbons with the double bond in the product alkene X m CH3 The real value of the Wittig reaction lies in its ability to yield an alkene of predictable structure, as the C=C bond is precisely where the C=O bond was in the reactant and no isomers (other than E/Z isomers)…

H3C. H3C. CH3 nnc» XT :OH 2 CH₂OH HCI catalyst Aldehydes and ketones react reversibly with two equivalents of alcohol in the presence of an acid catalyst to give acetals. Alcohols are poor nucleophiles, and so protonation of the carbonyl oxygen is used to make the carbonyl carbon a stronger electrophile. Addition of the first equivalent of alcohol gives a hemiacetal, a hydroxyether. Addition of the second equivalent of alcohol is accompanied by loss of water to yield the product acetal. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions CH3 H3C CH3OH H3CQ OCH3 CH3 H3C. H HO: :OCH 3 CH3 46

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Expert Solution & Answer

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Expert Solution & Answer

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Answer 5

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Answer 6

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Answer 7

Chapter 31.SE, Problem 33AP

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Answer 8

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Answer 9

Interpretation Introduction

Interpretation:

Draw the structure of pre-polymer and show the cross-linking effect of addition of pre-polymer to triamine.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is sodium chloride (NaCl).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 31.1 - Order the following monomers with respect to their...Ch. 31.1 - Order the following monomers with respect to their...Ch. 31.1 - Prob. 3P Ch. 31.2 - Prob. 4P Ch. 31.2 - Prob. 5P Ch. 31.3 - Prob. 6P Ch. 31.3 - Prob. 7P Ch. 31.4 - Prob. 8P Ch. 31.4 - Show the mechanism of the nucleophilic addition...Ch. 31.5 - Prob. 10P

Solution Summary: The author explains condensation polymerization, where two monomers react together to give rise to polymeric product by the release of small molecule.

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Chapter 31 Solutions