Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 31.SE, Problem 31AP
Interpretation Introduction

Interpretation:

Draw the representative segment of glyptal.

Concept introduction:

The type of polymerization occurring here is condensation polymerization. In this type of polymerization, two monomers react together to give rise to polymeric product by the release of small molecule. In this reaction the molecule which is released during this reaction is water (H2O).

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>Glyptal is a highly cross-linked thermosetting resin produced by heating glycerol and phthalic anhydride (1,2-benzenedicarboxylic acid anhydride). Show the structure of a representative segment of glyptal
What could be a potential use of adipic acid? A) Not much, adipic acid is a 1,6-dicarboxylic acid, so it easily decarboxylates. B) Adipic acid is extensively used in turophilic chemistry. C) Adipic acid is structurally related to sebacic acid. - We used sabacic acid to make 6,1d-Nylon. So if adipic acid were converted into its acid chloride, and then reacted with hexane-1,6-diamine, one could make 6,6-Nylon. D) Adipic acid is extremely toxic, so it is seldomly used in synthetic chemistry.
Propose a method to separate a mixture containing phenol, benzoic acid, naphthalene, and p-nitroaniline. Phenol is soluble in sodium hydroxide solution but insoluble in neutral water or sodium bicarbonate solution. Benzoic acid is soluble in either sodium hydroxide or sodium bicarbonate solutions. Write out the structures of the molecules in your scheme.
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