EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
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Question
Chapter 3, Problem 3.79EP
Interpretation Introduction
Interpretation:
The physical state of phenol at room temperature has to be characterized.
Expert Solution & Answer
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Students have asked these similar questions
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 3 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 3.1 - Prob. 1QQCh. 3.1 - Prob. 2QQCh. 3.2 - Prob. 1QQCh. 3.2 - Prob. 2QQCh. 3.2 - Prob. 3QQCh. 3.3 - Prob. 1QQCh. 3.3 - Prob. 2QQCh. 3.3 - Prob. 3QQCh. 3.3 - Prob. 4QQCh. 3.4 - Prob. 1QQ
Ch. 3.4 - Prob. 2QQCh. 3.4 - Prob. 3QQCh. 3.5 - Prob. 1QQCh. 3.5 - Prob. 2QQCh. 3.5 - Prob. 3QQCh. 3.5 - Prob. 4QQCh. 3.6 - Prob. 1QQCh. 3.6 - Prob. 2QQCh. 3.6 - Prob. 3QQCh. 3.7 - Prob. 1QQCh. 3.7 - Prob. 2QQCh. 3.8 - Prob. 1QQCh. 3.8 - Prob. 2QQCh. 3.9 - Prob. 1QQCh. 3.9 - Prob. 2QQCh. 3.9 - Prob. 3QQCh. 3.9 - Prob. 4QQCh. 3.9 - Prob. 5QQCh. 3.9 - Prob. 6QQCh. 3.10 - Prob. 1QQCh. 3.10 - Prob. 2QQCh. 3.11 - Prob. 1QQCh. 3.11 - Prob. 2QQCh. 3.11 - Prob. 3QQCh. 3.12 - Prob. 1QQCh. 3.12 - Prob. 2QQCh. 3.13 - Prob. 1QQCh. 3.13 - Prob. 2QQCh. 3.13 - Prob. 3QQCh. 3.14 - Prob. 1QQCh. 3.14 - Prob. 2QQCh. 3.14 - Prob. 3QQCh. 3.15 - Prob. 1QQCh. 3.15 - Prob. 2QQCh. 3.15 - Prob. 3QQCh. 3.15 - Prob. 4QQCh. 3.16 - Prob. 1QQCh. 3.16 - Prob. 2QQCh. 3.17 - Prob. 1QQCh. 3.17 - Prob. 2QQCh. 3.17 - Prob. 3QQCh. 3.18 - Prob. 1QQCh. 3.18 - Prob. 2QQCh. 3.18 - Prob. 3QQCh. 3.19 - Prob. 1QQCh. 3.19 - Prob. 2QQCh. 3.20 - Prob. 1QQCh. 3.20 - Prob. 2QQCh. 3.20 - Prob. 3QQCh. 3.20 - Prob. 4QQCh. 3.20 - Prob. 5QQCh. 3.21 - Prob. 1QQCh. 3.21 - Prob. 2QQCh. 3.21 - Prob. 3QQCh. 3.21 - Prob. 4QQCh. 3.21 - Prob. 5QQCh. 3 - Prob. 3.1EPCh. 3 - Indicate whether or not each of the following...Ch. 3 - Prob. 3.3EPCh. 3 - Prob. 3.4EPCh. 3 - Prob. 3.5EPCh. 3 - Prob. 3.6EPCh. 3 - Prob. 3.7EPCh. 3 - Prob. 3.8EPCh. 3 - Prob. 3.9EPCh. 3 - Prob. 3.10EPCh. 3 - Write a condensed structural formula for each of...Ch. 3 - Write a condensed structural formula for each of...Ch. 3 - Prob. 3.13EPCh. 3 - Prob. 3.14EPCh. 3 - Prob. 3.15EPCh. 3 - Prob. 3.16EPCh. 3 - Prob. 3.17EPCh. 3 - Prob. 3.18EPCh. 3 - Prob. 3.19EPCh. 3 - Prob. 3.20EPCh. 3 - Prob. 3.21EPCh. 3 - Prob. 3.22EPCh. 3 - Prob. 3.23EPCh. 3 - Prob. 3.24EPCh. 3 - Prob. 3.25EPCh. 3 - Prob. 3.26EPCh. 3 - Prob. 3.27EPCh. 3 - Prob. 3.28EPCh. 3 - Prob. 3.29EPCh. 3 - Prob. 3.30EPCh. 3 - Give the IUPAC name of the alcohol that fits each...Ch. 3 - Prob. 3.32EPCh. 3 - Prob. 3.33EPCh. 3 - Prob. 3.34EPCh. 3 - Prob. 3.35EPCh. 3 - Prob. 3.36EPCh. 3 - Prob. 3.37EPCh. 3 - Which member of each of the following pairs of...Ch. 3 - Prob. 3.39EPCh. 3 - Which member of each of the following pairs of...Ch. 3 - Determine the maximum number of hydrogen bonds...Ch. 3 - Prob. 3.42EPCh. 3 - Prob. 3.43EPCh. 3 - Prob. 3.44EPCh. 3 - Prob. 3.45EPCh. 3 - Prob. 3.46EPCh. 3 - Classify each of the following alcohols as a...Ch. 3 - Classify each of the following alcohols as a...Ch. 3 - Classify each of the following alcohols as a...Ch. 3 - Classify each of the following alcohols as a...Ch. 3 - Prob. 3.51EPCh. 3 - Prob. 3.52EPCh. 3 - Prob. 3.53EPCh. 3 - Prob. 3.54EPCh. 3 - Prob. 3.55EPCh. 3 - Prob. 3.56EPCh. 3 - Prob. 3.57EPCh. 3 - Prob. 3.58EPCh. 3 - Prob. 3.59EPCh. 3 - Prob. 3.60EPCh. 3 - The alcohol 2,2-dimethyl-1-butanol cannot be...Ch. 3 - Prob. 3.62EPCh. 3 - Prob. 3.63EPCh. 3 - Prob. 3.64EPCh. 3 - Prob. 3.65EPCh. 3 - Prob. 3.66EPCh. 3 - Prob. 3.67EPCh. 3 - Prob. 3.68EPCh. 3 - Prob. 3.69EPCh. 3 - Prob. 3.70EPCh. 3 - Prob. 3.71EPCh. 3 - Prob. 3.72EPCh. 3 - Prob. 3.73EPCh. 3 - Prob. 3.74EPCh. 3 - Prob. 3.75EPCh. 3 - Prob. 3.76EPCh. 3 - Prob. 3.77EPCh. 3 - Prob. 3.78EPCh. 3 - Prob. 3.79EPCh. 3 - Prob. 3.80EPCh. 3 - Prob. 3.81EPCh. 3 - Prob. 3.82EPCh. 3 - Prob. 3.83EPCh. 3 - Prob. 3.84EPCh. 3 - Prob. 3.85EPCh. 3 - Prob. 3.86EPCh. 3 - Prob. 3.87EPCh. 3 - Prob. 3.88EPCh. 3 - Prob. 3.89EPCh. 3 - Prob. 3.90EPCh. 3 - Classify each of the following compounds as an...Ch. 3 - Prob. 3.92EPCh. 3 - Draw or write the following for the simplest ether...Ch. 3 - Draw or write the following for the simplest ether...Ch. 3 - Prob. 3.95EPCh. 3 - Prob. 3.96EPCh. 3 - Assign a common name to each of the ethers in...Ch. 3 - Prob. 3.98EPCh. 3 - Prob. 3.99EPCh. 3 - Prob. 3.100EPCh. 3 - Prob. 3.101EPCh. 3 - Prob. 3.102EPCh. 3 - Prob. 3.103EPCh. 3 - Prob. 3.104EPCh. 3 - Prob. 3.105EPCh. 3 - Prob. 3.106EPCh. 3 - Prob. 3.107EPCh. 3 - Prob. 3.108EPCh. 3 - Prob. 3.109EPCh. 3 - Prob. 3.110EPCh. 3 - Prob. 3.111EPCh. 3 - Prob. 3.112EPCh. 3 - Prob. 3.113EPCh. 3 - Prob. 3.114EPCh. 3 - How many isomeric ethers exist when the R groups...Ch. 3 - Prob. 3.116EPCh. 3 - Prob. 3.117EPCh. 3 - Prob. 3.118EPCh. 3 - Prob. 3.119EPCh. 3 - Prob. 3.120EPCh. 3 - Dimethyl ether and ethanol have the same molecular...Ch. 3 - Prob. 3.122EPCh. 3 - Prob. 3.123EPCh. 3 - Prob. 3.124EPCh. 3 - Prob. 3.125EPCh. 3 - Prob. 3.126EPCh. 3 - Classify each of the following molecular...Ch. 3 - Classify each of the following molecular...Ch. 3 - Prob. 3.129EPCh. 3 - Prob. 3.130EPCh. 3 - Prob. 3.131EPCh. 3 - Draw a condensed structural formula for each of...Ch. 3 - Prob. 3.133EPCh. 3 - Prob. 3.134EPCh. 3 - Prob. 3.135EPCh. 3 - Write the formulas for the sulfur-containing...Ch. 3 - Prob. 3.137EPCh. 3 - For each of the following pairs of compounds,...Ch. 3 - Prob. 3.139EPCh. 3 - Prob. 3.140EPCh. 3 - Prob. 3.141EPCh. 3 - Prob. 3.142EPCh. 3 - Prob. 3.143EPCh. 3 - Prob. 3.144EPCh. 3 - Prob. 3.145EPCh. 3 - Prob. 3.146EP
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