Concept explainers
(a)
Interpretation:
The structural formula for the given phenol has to be drawn.
Concept Introduction:
When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.
Phenol derivative with one substituent:
IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.
Ortho- means disubstitution in 1,2
Meta- means disubstitution in 1,3
Para- means disubstitution in 1,4
In all the above derivatives of phenol, the first position is occupied by hydroxyl group.
Phenol derivatives with two or more substituents:
More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.
By considering the way the phenol is named, the structure can be drawn if the name is given.
(b)
Interpretation:
The structural formula for the given phenol has to be drawn.
Concept Introduction:
When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.
Phenol derivative with one substituent:
IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.
Ortho- means disubstitution in 1,2
Meta- means disubstitution in 1,3
Para- means disubstitution in 1,4
In all the above derivatives of phenol, the first position is occupied by hydroxyl group.
Phenol derivatives with two or more substituents:
More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.
By considering the way the phenol is named, the structure can be drawn if the name is given.
(c)
Interpretation:
The structural formula for the given phenol has to be drawn.
Concept Introduction:
When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.
Phenol derivative with one substituent:
IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.
Ortho- means disubstitution in 1,2
Meta- means disubstitution in 1,3
Para- means disubstitution in 1,4
In all the above derivatives of phenol, the first position is occupied by hydroxyl group.
Phenol derivatives with two or more substituents:
More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.
By considering the way the phenol is named, the structure can be drawn if the name is given.
(d)
Interpretation:
The structural formula for the given phenol has to be drawn.
Concept Introduction:
When one hydrogen atoms are replaced by a hydroxyl group in benzene is known as phenol. If the other hydrogen atoms present in phenol are replaced by other atoms or groups are known as phenol derivatives.
Phenol derivative with one substituent:
IUPAC system of naming phenol derivative considers phenol to be a part of main name. The numbering is given in a way that the substituent gets the least numbering possible.
Ortho- means disubstitution in 1,2
Meta- means disubstitution in 1,3
Para- means disubstitution in 1,4
In all the above derivatives of phenol, the first position is occupied by hydroxyl group.
Phenol derivatives with two or more substituents:
More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.
By considering the way the phenol is named, the structure can be drawn if the name is given.
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Chapter 3 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
- There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…arrow_forwardA mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ Marrow_forwardWhat units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?arrow_forward
- Provide the structure, circle or draw, of the monomeric unit found in the biological polymeric materials given below. HO OH amylose OH OH 행 3 HO cellulose OH OH OH Ho HOarrow_forwardWhat units (if any) does K have? Does K depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)? in calculating the response factorarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
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