The predominant organic product that is formed in the given reaction has to be written. Concept Introduction: Alcohol is an organic compound that has hydroxyl as its functional group . Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds. Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

Question

3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.

Answer 1

Question

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

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3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.

1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat

3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Answer 2

Question

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

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Answer 3

Question

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

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Answer 4

Question

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

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Answer 5

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

Answer 6

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

Answer 7

Chapter 3, Problem 3.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

Answer 8

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

Answer 9

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

Answer 10

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

Answer 11

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound. Addition of hydrogen to this carbonyl group leads to the formation of alcohol. When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group. A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

Answer 12

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

Answer 13

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms. When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product. The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule. The general scheme for hydration of alkene can be given as,

Answer 14

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Ch. 3.1 - Prob. 1QQ Ch. 3.1 - Prob. 2QQ Ch. 3.2 - Prob. 1QQ Ch. 3.2 - Prob. 2QQ Ch. 3.2 - Prob. 3QQ Ch. 3.3 - Prob. 1QQ Ch. 3.3 - Prob. 2QQ Ch. 3.3 - Prob. 3QQ Ch. 3.3 - Prob. 4QQ Ch. 3.4 - Prob. 1QQ

Solution Summary: The author explains that alcohol is an organic compound that has hydroxyl as its functional group. Alcohols can be prepared by hydration of alkenes and reduction of carbonyl compounds.

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