(a) Interpretation: The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated. Concept introduction: An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

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Answer 1

Question

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

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Answer 2

Question

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

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Answer 3

Question

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

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Answer 4

Question

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

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Answer 5

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 6

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 7

Chapter 27, Problem 27.79AP

Interpretation Introduction

(a)

Interpretation:

The primary structure of P which contains an unusual peptide bond is to be stated. The consistency of the structure P with the 17 mass-unit difference is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reaction between two peptide chains within the pilus is to be shown. The mechanism of the corresponding reaction is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between peptides A and the peptide B do not occur at physiological pH at rapid rate is to be stated.

Concept introduction:

An amide bond formed between a carboxyl group present on the side chain of an amino acid and the amine group present on the side chain of an amino acid is known as an isopeptide bond.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 27 - Prob. 27.1P Ch. 27 - Prob. 27.2P Ch. 27 - Prob. 27.3P Ch. 27 - Prob. 27.4P Ch. 27 - Prob. 27.5P Ch. 27 - Prob. 27.6P Ch. 27 - Prob. 27.8P Ch. 27 - Prob. 27.9P Ch. 27 - Prob. 27.10P Ch. 27 - Prob. 27.11P

Solution Summary: The author explains the structure of P, which contains an unusual peptide bond, and the mechanism of the corresponding reaction.

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Chapter 27 Solutions