(a) Interpretation: The resonance structure of carbocation intermediate in Eq.27.48 is to be shown. Concept Introduction: Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

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Answer 1

Question

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Answer 2

Question

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

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Answer 3

Question

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

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Answer 4

Question

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

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Answer 5

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

Answer 6

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Answer 7

Chapter 27, Problem 27.34P

Interpretation Introduction

(a)

Interpretation:

The resonance structure of carbocation intermediate in Eq.27.48 is to be shown.

Concept Introduction:

Resonance structure of a compound can be formed by the donation of lone pair of an atom to other atom having positive charge or empty orbital. The original structure of a molecule is a hybrid of different resonance structure.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

Answer 9

Interpretation Introduction

(b)

Interpretation:

The role of Mn2+ in the glycosylation reaction is to be stated.

Concept Introduction:

Proteins get attached with oligosaccharide to form glycoproteins. The attachment of saccharide to a protein is known as glycosylation. There are two types of glycosylation, N-glycosylation and O-glycosylation. Some O-glycosylation involve inversion of the configuration and some involve retention of the configuration

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 27 - Prob. 27.1P Ch. 27 - Prob. 27.2P Ch. 27 - Prob. 27.3P Ch. 27 - Prob. 27.4P Ch. 27 - Prob. 27.5P Ch. 27 - Prob. 27.6P Ch. 27 - Prob. 27.8P Ch. 27 - Prob. 27.9P Ch. 27 - Prob. 27.10P Ch. 27 - Prob. 27.11P

Solution Summary: The author explains the resonance structure of the carbocation intermediate in Eq.27.48.

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Chapter 27 Solutions