(a) Interpretation: The given compounds are to be arranged in order of increasing basicity. Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

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Answer 1

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Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

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Br HO ? HO ✓ OH

Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow. Group #1: Buffer pH = 4.35 Group #2: Buffer pH = 4.70 Group #3: Buffer pH = 5.00 Group #4: Buffer pH = 5.30 Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following: a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above. b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?) c) explain your choice

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Answer 2

Question

Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

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Answer 3

Question

Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

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Answer 4

Question

Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

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Answer 5

Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 6

Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 7

Chapter 25, Problem 25.47P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 12

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 13

Interpretation Introduction

(d)

Interpretation: The given compounds are to be arranged in order of increasing basicity.

Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electron are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.

Answer 14

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Answer 16

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Answer 17

Ch. 25 - Prob. 25.1P Ch. 25 - Draw the structure of a compound of molecular...Ch. 25 - Prob. 25.3P Ch. 25 - Prob. 25.4P Ch. 25 - Prob. 25.5P Ch. 25 - Arrange the compounds in order of increasing...Ch. 25 - Prob. 25.7P Ch. 25 - Prob. 25.8P Ch. 25 - Problem 25.7 Draw the product of each...Ch. 25 - Prob. 25.10P

Solution Summary: The author explains the arrangement of compounds in order of increasing basicity. Aniline is the least basic compound due to the delocalization of electrons present on nitrogen atom.

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