(a) Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified. Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R − NH 2 . Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group. In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group. In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Question

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Answer 1

Question

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

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Answer 2

Question

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

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Answer 3

Question

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

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Answer 4

Question

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

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Answer 5

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

Answer 6

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Answer 7

Chapter 25, Problem 25.1P

Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 8

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 1

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 2

Figure 1

In spermine, four nitrogen atoms are present. Among these four nitrogen atoms, two are primary amines that contain one alkyl group on nitrogen atom and two are secondary amines that contain two alkyl groups on nitrogen atom as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 3

Figure 2

Answer 13

Conclusion

In spermine, primary and secondary amines are present as shown in Figure 2.

Answer 14

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

Answer 15

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 16

Expert Solution

Answer to Problem 25.1P

Each amine in the given compound is classified as,

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 4

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The given compound is shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 5

Figure 3

Meperidine contains one nitrogen atom bonded to three alkyl groups. Hence, it is a tertiary amine as shown below.

Organic Chemistry, Chapter 25, Problem 25.1P , additional homework tip 6

Figure 4

Answer 21

Conclusion

In meperidine, tertiary amine is present as shown in Figure 4.

Answer 22

Ch. 25 - Prob. 25.1P Ch. 25 - Draw the structure of a compound of molecular...Ch. 25 - Prob. 25.3P Ch. 25 - Prob. 25.4P Ch. 25 - Prob. 25.5P Ch. 25 - Arrange the compounds in order of increasing...Ch. 25 - Prob. 25.7P Ch. 25 - Prob. 25.8P Ch. 25 - Problem 25.7 Draw the product of each...Ch. 25 - Prob. 25.10P

Solution Summary: The author explains that amines can be classified as primary, secondary, or tertiary.

Answer to Problem 25.1P

Explanation of Solution

Answer to Problem 25.1P

Explanation of Solution

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Chapter 25 Solutions