The stepwise mechanism for the given reaction is to be devised. Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β -ketoester.

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Answer 1

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Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

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Answer 2

Question

Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

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Answer 3

Question

Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

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Answer 4

Question

Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

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Answer 5

Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

Answer 6

Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

Answer 7

Chapter 24, Problem 24.75P

Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be devised.

Concept introduction: Dieckmann condensation reaction is an intramolecular condensation reaction in diester. In Dieckmann condensation reaction, the base abstracts the acidic proton from α carbon atom of one ester group to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of β-ketoester.

Answer 8

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Answer 11

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 24 - Acid-catalyzed dehydration of hydroxy carbonyl...Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Problem 24.8 Draw the products formed in the...Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that the stepwise mechanism for the given reaction is shown in Figure 1.

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Chapter 24 Solutions