Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Question
Chapter 24, Problem 24.58P
Interpretation Introduction
Interpretation:
A stepwise mechanism for the formation of one C − C bond in polutulipalin is to be drawn.
Concept introduction:
The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with
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Can you explain condensation polymerization and give an example with structure of one with 2 carboxylic acid groups and 2 OH groups.
The plastic known as PETE (polyethyleneterephthalate) is used to make plastic soft drink bottles and containers for salad dressing, shampoos, and dishwashing liquids. PETE is a polymer of terephthalic acid and ethylene glycol. Today, PETE is the most widely recycled of all the plastics. After it is separated from other plastics, PETE can be used in polyester fabric, door mats, and tennis ball containers. In 2015, 1.84×109 lb1.84×109 lb of PETE bottles were recycled in the U.S. The density of PETE is 1.38 g/mLg/mL.
What volume, in liters, of PETE bottles were recycled in 2015 in the U.S.?
Express your answer to three significant figures.
The plastic known as PETE (polyethyleneterephthalate) is used to make plastic soft drink bottles and containers for salad dressing, shampoos, and dishwashing liquids. PETE is a polymer of terephthalic acid and ethylene glycol. Today, PETE is the most widely recycled of all the plastics. After it is separated from other plastics, PETE can be used in polyester fabric, door mats, and tennis ball containers. In 2015, 1.84×109 lb1.84×109 lb of PETE bottles were recycled in the U.S. The density of PETE is 1.38 g/mLg/mL.
Suppose a landfill holds 2.6×107 L2.6×107 L of recycled PETE. If all the PETE bottles recycled in 2015 in the U.S. were placed instead in landfills, how many landfills would be needed?
Express your answer as an integer.
Chapter 24 Solutions
Organic Chemistry
Ch. 24 - Prob. 24.1PCh. 24 - Prob. 24.2PCh. 24 - Problem 24.3
What unsaturated carbonyl compound is...Ch. 24 - Acid-catalyzed dehydration of hydroxy carbonyl...Ch. 24 - Prob. 24.5PCh. 24 - Prob. 24.6PCh. 24 - Prob. 24.7PCh. 24 - Problem 24.8
Draw the products formed in the...Ch. 24 - Prob. 24.9PCh. 24 - Prob. 24.10P
Ch. 24 - Prob. 24.11PCh. 24 - Prob. 24.12PCh. 24 - Prob. 24.13PCh. 24 - Prob. 24.14PCh. 24 - Problem 24.16
What ester is formed when each...Ch. 24 - What crossed Claisen product is formed from each...Ch. 24 - Prob. 24.17PCh. 24 -
Draw the products of each reaction.
a. b.
Ch. 24 - Problem 24.20
Two steps in a synthesis of the...Ch. 24 - Prob. 24.20PCh. 24 - Problem 24.22
Which of the following compounds can...Ch. 24 - What product is formed when each pair of compounds...Ch. 24 - Problem 24.24
What starting materials are needed...Ch. 24 - Problem 24.25
Draw the products when each pair of...Ch. 24 - Problem 24.27
What starting materials are needed...Ch. 24 - Prob. 24.26PCh. 24 - 24.29 What steps are needed to convert A to B?
Ch. 24 - Prob. 24.28PCh. 24 - Prob. 24.29PCh. 24 - 24.31 Draw the product formed in each directed...Ch. 24 - Prob. 24.31PCh. 24 - What starting materials are needed to synthesize...Ch. 24 - Prob. 24.33PCh. 24 - Prob. 24.34PCh. 24 - Prob. 24.35PCh. 24 - 24.36 Identify the structures of C and D in the...Ch. 24 - Prob. 24.37PCh. 24 - Prob. 24.38PCh. 24 - Prob. 24.39PCh. 24 - Draw the product formed from a Claisen reaction...Ch. 24 - Prob. 24.41PCh. 24 - 24.41 Even though B contains three ester groups, a...Ch. 24 - Prob. 24.43PCh. 24 - What starting materials are needed to prepare each...Ch. 24 - 24.44 Vetivone is isolated from vetiver, a...Ch. 24 - Draw the product of each Robinson annulation from...Ch. 24 - Prob. 24.47PCh. 24 - Draw the organic products formed when butanal...Ch. 24 - 24.47 Draw the organic products formed in each...Ch. 24 - 24.48 Fill in the lettered reagents needed for...Ch. 24 - Prob. 24.51PCh. 24 - Prob. 24.52PCh. 24 - Prob. 24.53PCh. 24 - Draw a stepwise mechanism for the following...Ch. 24 - Prob. 24.55PCh. 24 - Prob. 24.56PCh. 24 - Prob. 24.57PCh. 24 - Prob. 24.58PCh. 24 - Prob. 24.59PCh. 24 - Prob. 24.60PCh. 24 - Prob. 24.61PCh. 24 - Prob. 24.62PCh. 24 - Devise a synthesis of each compound from...Ch. 24 - Prob. 24.64PCh. 24 - Prob. 24.65PCh. 24 - Prob. 24.66PCh. 24 - 24.65 Answer the following questions about...Ch. 24 - Prob. 24.68PCh. 24 - Prob. 24.69PCh. 24 - Prob. 24.70PCh. 24 - Prob. 24.71PCh. 24 - 24.70 Draw a stepwise mechanism for the following...Ch. 24 - Prob. 24.73PCh. 24 - Prob. 24.74PCh. 24 - Prob. 24.75P
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Similar questions
- The plastic known as PETE (polyethyleneterephthalate) is used to make plastic soft drink bottles and containers for salad dressing, shampoos, and dishwashing liquids. PETE is a polymer of terephthalic acid and ethylene glycol. Today, PETE is the most widely recycled of all the plastics. After it is separated from other plastics, PETE can be used in polyester fabric, door mats, and tennis ball containers. In 2015, 1.84×109 lb1.84×109 lb of PETE bottles were recycled in the U.S. The density of PETE is 1.38 g/mLg/mL. If 2.74×109 kg2.74×109 kg of PETE bottles were sold in 2015, what percentage of those bottles were recycled? Express your answer to three significant figures.arrow_forwardWhat monomer is needed to form each polymer? COOEt COOEt cOOEt Et = CH,CH3 polyisobutylene (used to make basketballs) poly(ethyl acrylate) (used in latex paints)arrow_forwardWhat monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?arrow_forward
- Draw the structure of the polymer formed from ring-opening metathesis polymerization (ROMP) of each monomer.arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. Give the structures of poly(vinyl acetate) and poly(vinyl alcohol)arrow_forwardGeneral polymerization processes. Describe stepwise polymerization and chain polymerization.arrow_forward
- A particularly strong and rigid polyester used for electronic parts is marketed under the trade name Glyptal. It is a polymer of terephthalic acid and glycerol. Draw a segment of the polymer and explain why it is so strong.arrow_forwardPolypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene. Poiypropylene belongs to the group of polyolefins and is partialy crystalline and non-polar. CH, -CH,CH-CH,CH–CH,CH-CH,CH-CH,CH-CH,CH- ÇH, ÇH, CH, CH, Draw the syndiotactic and isotactic forms of PP.arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. We have seen that basic hydrolysis destroys the Dacron polymer. Poly(vinyl acetate) is converted to poly(vinyl alcohol) by a basic hydrolysis of the ester groups. Why doesn’t the hydrolysis destroy the poly(vinyl alcohol)polymer?arrow_forward
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