Chapter 25, Problem 25.26P

Interpretation Introduction

(a)

Interpretation: The products formed by the reaction of given compound with ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{2}}{\text{NH}}_{\text{2}}$ and ${\left({\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\right)}_{\text{2}}\text{NH}$ are to be drawn.

Concept introduction: Amines on reaction with acid chlorides and anhydride form amide whereas on reaction with ketones and aldehydes they form imine or enamine. Primary and secondary amines on reaction with ketone and aldehyde form imine and enamine, respectively.

Interpretation Introduction

(b)

Interpretation: The products formed by the reaction of given compound with ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{2}}{\text{NH}}_{\text{2}}$ and ${\left({\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\right)}_{\text{2}}\text{NH}$ are to be drawn.

Concept introduction: Amines on reaction with acid chlorides and anhydride form amide whereas on reaction with ketones and aldehydes they form imine or enamine. Primary and secondary amines on reaction with ketone and aldehyde form imine and enamine, respectively.

Interpretation Introduction

(c)

Interpretation: The products formed by the reaction of given compound with ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{2}}{\text{NH}}_{\text{2}}$ and ${\left({\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\right)}_{\text{2}}\text{NH}$ are to be drawn.

Concept introduction: Amines on reaction with acid chlorides and anhydride form amide whereas on reaction with ketones and aldehydes they form imine or enamine. Primary and secondary amines on reaction with ketone and aldehyde form imine and enamine, respectively.