Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 2.5, Problem 19ATS
Interpretation Introduction

Interpretation:

The identification of lone pair in Amino acid has to be done.

Concept Introduction:

Lone pair:

A lone pair is given by a pair of outer most electrons that are not shared with another atom, otherwise called as non bonding pair. These are generally found in the valence shell of atom and are identified by Lewis structure. Pairs of electrons are considered as lone pairs when two electrons are paired and are not participated in chemical bonding. The sum of number of lone pairs and number of bonding electrons equals the total number of outermost electrons around an atom.

Delocalized lone pair:

The lone pair that participates in resonance is called as delocalized lone pair. The presence of lone pair affects the geometry of the atom.

Localized lone pair:

The lone pair that doesn’t participate in the resonance is called localized lone pair. The lone pair is not allylic to π bond.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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