Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 2.8, Problem 21PTS
Interpretation Introduction

Interpretation:

The violation in the curved arrows has to be checked.

Concept Introduction:

Curved arrows:

The necessary tools to draw perfect resonance structure are curved arrows. Curved arrows don’t represent the flow of electrons.  A tail and a head can be seen in curved arrow.

A head and tail of every arrow are to be drawn in the exact location. The tail represents where the electrons are originated, and the head represents the place where the electrons are going.

Rules for the curved arrow:

  1. 1) The breaking of single bond should be avoided.
  2. 2) The octet should never be exceeding for second row elements.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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