Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 2, Problem 53PP

(a)

Interpretation Introduction

Interpretation: For the given set of molecules the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons in the bond are shared equally between the respective atoms

The sharing of electrons is done irrespective of the electronegativity of an atom.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

Valence electrons represent the electrons present in the valence orbital of an atom.

Non bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

(b)

Interpretation Introduction

Interpretation: For the given set of molecules the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons in the bond are shared equally between the respective atoms

The sharing of electrons is done irrespective of the electronegativity of an atom.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

Valence electrons represent the electrons present in the valence orbital of an atom.

Non bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

(c)

Interpretation Introduction

Interpretation: For the given set of molecules the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons in the bond are shared equally between the respective atoms

The sharing of electrons is done irrespective of the electronegativity of an atom.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

Valence electrons represent the electrons present in the valence orbital of an atom.

Non bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

(d)

Interpretation Introduction

Interpretation: For the given set of molecules the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons in the bond are shared equally between the respective atoms

The sharing of electrons is done irrespective of the electronegativity of an atom.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

Valence electrons represent the electrons present in the valence orbital of an atom.

Non bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

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2. Write a complete mechanism for the reaction shown below. NaOCH LOCH₁ O₂N NO2 CH₂OH, 20 °C O₂N NO2
4. Propose a synthesis of the target molecules from the respective starting materials. a) b) LUCH C Br OH

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