Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 2.11, Problem 8LTS
Interpretation Introduction
Interpretation:
The significant resonance structure has to be drawn.
Concept Introduction:
Resonance is a method to relating to describe about delocalized electrons inside certain molecules or polyatomic ions where the Lewis structure can’t be expressed. A molecule or ion containing delocalized electrons can be represented by using several similar structures such structures are called as resonance structures or canonical structures.
The delocalization of electron lowers the potential energy of the substance and making it more stable than any of the contributing structures. The variation in the potential energy of the actual structure and that of resemblance structure with lowest potential energy is known as resonance energy or delocalization energy.
Rules to determine significant resonance structure:
- 1) Decrease the charges
- 2) Presence of octet electrons in electronegative atoms such as Oxygen, Nitrogen and Chlorine bearing a positive charge.
- 3) Resonance structures should be avoided for two Carbon atoms bearing opposite charges.
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6. Consider the following exothermic reaction below.
2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq)
a. If Cul is added, there will be a shift left/shift right/no shift (circle one).
b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one).
c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one).
d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle
one). Hint: one of the reaction species is more soluble in hexane than in water.
e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one).
f. Which of the changes above will change the equilibrium constant, K?
Chapter 2 Solutions
Organic Chemistry, Binder Ready Version
Ch. 2.1 - Prob. 1LTSCh. 2.1 - Prob. 1PTSCh. 2.1 - Prob. 2ATSCh. 2.1 - Prob. 3ATSCh. 2.1 - Prob. 4ATSCh. 2.2 - Prob. 2LTSCh. 2.2 - Prob. 5PTSCh. 2.2 - Prob. 6ATSCh. 2.2 - Prob. 7ATSCh. 2.2 - Prob. 3LTS
Ch. 2.2 - Prob. 8PTSCh. 2.2 - Prob. 9ATSCh. 2.2 - Prob. 10ATSCh. 2.3 - Prob. 11CCCh. 2.4 - Prob. 12CCCh. 2.4 - Prob. 13CCCh. 2.5 - Prob. 4LTSCh. 2.5 - Prob. 14PTSCh. 2.5 - Prob. 15ATSCh. 2.5 - Prob. 5LTSCh. 2.5 - Prob. 16PTSCh. 2.5 - Prob. 17ATSCh. 2.5 - Prob. 18ATSCh. 2.5 - Prob. 19ATSCh. 2.6 - Prob. 20CCCh. 2.8 - Prob. 6LTSCh. 2.8 - Prob. 21PTSCh. 2.8 - Prob. 22ATSCh. 2.9 - Prob. 7LTSCh. 2.9 - Prob. 23PTSCh. 2.9 - Prob. 24ATSCh. 2.10 - Prob. 25CCCh. 2.10 - Prob. 26CCCh. 2.10 - Prob. 27CCCh. 2.10 - Prob. 28CCCh. 2.10 - Prob. 29CCCh. 2.10 - Prob. 30CCCh. 2.10 - Prob. 31CCCh. 2.10 - Prob. 32CCCh. 2.11 - Prob. 8LTSCh. 2.11 - Prob. 33PTSCh. 2.11 - Prob. 34ATSCh. 2.11 - Prob. 35ATSCh. 2.12 - Prob. 9LTSCh. 2.12 - Prob. 36PTSCh. 2.12 - Prob. 37ATSCh. 2.12 - Prob. 38ATSCh. 2 - Prob. 39PPCh. 2 - Prob. 40PPCh. 2 - Prob. 41PPCh. 2 - Prob. 42PPCh. 2 - Prob. 43PPCh. 2 - Prob. 44PPCh. 2 - Prob. 45PPCh. 2 - Prob. 46PPCh. 2 - Prob. 47PPCh. 2 - Prob. 48PPCh. 2 - Prob. 49PPCh. 2 - Prob. 50PPCh. 2 - Prob. 51PPCh. 2 - Prob. 52PPCh. 2 - Prob. 53PPCh. 2 - Prob. 54PPCh. 2 - Prob. 55PPCh. 2 - Prob. 56PPCh. 2 - Prob. 57PPCh. 2 - Prob. 58PPCh. 2 - Prob. 59PPCh. 2 - Prob. 60PPCh. 2 - Prob. 61PPCh. 2 - Prob. 62PPCh. 2 - Prob. 65IPCh. 2 - Prob. 66IPCh. 2 - Prob. 67IP
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