Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 2.11, Problem 8LTS
Interpretation Introduction

Interpretation:

The significant resonance structure has to be drawn.

Concept Introduction:

Resonance is a method to relating to describe about delocalized electrons inside certain molecules or polyatomic ions where the Lewis structure can’t be expressed. A molecule or ion containing delocalized electrons can be represented by using several similar structures such structures are called as resonance structures or canonical structures.

The delocalization of electron lowers the potential energy of the substance and making it more stable than any of the contributing structures. The variation in the potential energy of the actual structure and that of resemblance structure with lowest potential energy is known as resonance energy or delocalization energy.

Rules to determine significant resonance structure:

  1. 1) Decrease the charges
  2. 2) Presence of octet electrons in electronegative atoms such as Oxygen, Nitrogen and Chlorine bearing a positive charge.
  3. 3) Resonance structures should be avoided for two Carbon atoms bearing opposite charges.

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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 164 of N Select to Add Arrows CHI CH 1 1 1 P
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