Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 2, Problem 56PP
Interpretation Introduction

Interpretation:

Relationship between two given structure has to be analyzed for the existence of isomeric or resonance relationship.

Concept introduction:

Resonance structures: Resonance structures are electrically equivalent Lewis structures. Formal charges on these structures are same, these structures represented through a double headed arrow between the structures. Resonance structures are resulted during the delocalization of pi-electrons in the compound.

Constitutional isomers: Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

To find: the relationship between the given two structures.

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2. Write a complete mechanism for the reaction shown below. NaOCH LOCH₁ O₂N NO2 CH₂OH, 20 °C O₂N NO2
4. Propose a synthesis of the target molecules from the respective starting materials. a) b) LUCH C Br OH
The following mechanism for the gas phase reaction of H2 and ICI that is consistent with the observed rate law is: step 1 step 2 slow: H2(g) +ICI(g) → HCl(g) + HI(g) fast: ICI(g) + HI(g) → HCl(g) + |2(g) (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + → + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A][B]"..., where '1' is understood (so don't write it) for m, n etc.) Rate =

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Organic Chemistry, Binder Ready Version

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