Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 2.2, Problem 8PTS

(a)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(b)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(c)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(d)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(e)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(f)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(g)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(h)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(i)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(j)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(k)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(l)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(m)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(n)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(o)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(p)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(q)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

(r)

Interpretation Introduction

Interpretation:

The bond line for the constitutional isomer has to be given.

Concept Introduction:

A Bond-line structure is one of the direct methods of writing the structural formula for organic compounds.

Rules to draw Bond-line structure:

Zigzag format should be followed for the Carbon atoms in straight line.

Double bonds should be drawn as far away from each other as possible.

The direction in which the single bonds are drawn is irrelevant.

Heteroatoms and Hydrogen attached to the heteroatom should be drawn.

A Carbon atom must not be drawn with more than four bonds, since Carbon has only four orbitals in its outer most shell and hence, Carbon atoms can form only four bonds.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Organic Chemistry, Binder Ready Version

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