How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown. Concept introduction: Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene. To show: How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene). Answer: The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below. Explanation: Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag 2 O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene. Conclusion: The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

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Answer 1

Question

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

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Answer 2

Question

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Expert Solution & Answer

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Answer 3

Question

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Answer 6

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Answer 7

Chapter 24.SE, Problem 76AP

Interpretation Introduction

Interpretation:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene) is to be shown.

Concept introduction:

Two successive Hofmann elimination reactions of with quarternary ammonium salt of tropidene will yield tropilidene.

To show:

How to convert tropidene in to tropilidene (1,3,5-cycloheptatriene).

Answer:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Explanation:

Tropidene when treated with excess of methyl iodide yields a quartenary ammonium salt which undergoes Hofmann elimination when heated with Ag₂O and water to produce N,N-dimethylcycloheptadiene. Methylation of the diene with excess of methyl iodide yields another quartenary ammonium salt which undergoes Hofmann elimination reaction to yield tropilidene.

Conclusion:

The conversion of tropidene in to tropilidene (1,3,5-cycloheptatriene) is given below.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

Solution Summary: The author explains how to convert tropidene into a quartenary ammonium salt, which undergoes Hofmann elimination when heated with Ag 2 O and water to produce N,N-dimethylcyclo

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Chapter 24 Solutions