Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Question
Chapter 24.SE, Problem 50AP
Interpretation Introduction
Interpretation:
To draw the structure of the pyrrole.
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Because amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.
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CH3 CH2 CH2NH2
is a Brønsted
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Its water
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are basic.
All
substances
containing
nitrogen
atoms are
Brønsted
bases.
This
amine is a
proton
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This
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ассеpt a
proton
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Draw the reactions for the following products (any or all) (include all products).
Chapter 24 Solutions
Organic Chemistry
Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2PCh. 24.1 - Prob. 3PCh. 24.3 - Prob. 4PCh. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6PCh. 24.5 - Prob. 7PCh. 24.6 - Prob. 8PCh. 24.6 - Prob. 9PCh. 24.6 - Show two methods for the synthesis of dopamine, a...
Ch. 24.6 - Prob. 11PCh. 24.6 - Prob. 12PCh. 24.6 - Prob. 13PCh. 24.7 - Prob. 14PCh. 24.7 - Prob. 15PCh. 24.8 - Prob. 16PCh. 24.8 - Propose syntheses of the following compounds from...Ch. 24.8 - How would you prepare the following compounds from...Ch. 24.8 - Prob. 19PCh. 24.9 - Draw an orbital picture of thiazole. Assume that...Ch. 24.9 - Prob. 21PCh. 24.9 - Prob. 22PCh. 24.9 - Which nitrogen atom in the hallucinogenic indole...Ch. 24.9 - Prob. 24PCh. 24.10 - Prob. 25PCh. 24.SE - Name the following amines, and identify each as...Ch. 24.SE - The following compound contains three nitrogen...Ch. 24.SE - Name the following amine, including R, S...Ch. 24.SE - Prob. 29VCCh. 24.SE - Predict the product(s) for each reaction below and...Ch. 24.SE - Predict the product(s) and provide the complete...Ch. 24.SE - Prob. 32MPCh. 24.SE - Predict the product(s) and provide the mechanism...Ch. 24.SE - The diazotization of aniline first involves the...Ch. 24.SE - Prob. 35MPCh. 24.SE - Prob. 36MPCh. 24.SE - Prob. 37MPCh. 24.SE - Prob. 38MPCh. 24.SE - Choline, a component of the phospholipids in cell...Ch. 24.SE - Prob. 40MPCh. 24.SE - -Amino acids can be prepared by the Strecker...Ch. 24.SE - Prob. 42MPCh. 24.SE - Prob. 43MPCh. 24.SE - Prob. 44MPCh. 24.SE - Propose a mechanism for the following reaction:Ch. 24.SE - Prob. 46MPCh. 24.SE - Name the following compounds:Ch. 24.SE - Prob. 48APCh. 24.SE - Prob. 49APCh. 24.SE - Prob. 50APCh. 24.SE - Histamine, whose release in the body triggers...Ch. 24.SE - Prob. 52APCh. 24.SE - Prob. 53APCh. 24.SE - Prob. 54APCh. 24.SE - Prob. 55APCh. 24.SE - Prob. 56APCh. 24.SE - Prob. 57APCh. 24.SE - Prob. 58APCh. 24.SE - Prob. 59APCh. 24.SE - Prob. 60APCh. 24.SE - Show the products from reaction of p-bromoaniline...Ch. 24.SE - Prob. 62APCh. 24.SE - How would you prepare the following compounds from...Ch. 24.SE - Prob. 64APCh. 24.SE - Phenacetin, a substance formerly used in...Ch. 24.SE - Prob. 66APCh. 24.SE - Draw the structure of the amine that produced the...Ch. 24.SE - Fill in the missing reagents a-e in the following...Ch. 24.SE - Prob. 69APCh. 24.SE - Prob. 70APCh. 24.SE - Deduce the structure of the compound with formula...Ch. 24.SE - Prob. 72APCh. 24.SE - Prob. 73APCh. 24.SE - Prob. 74APCh. 24.SE - Prob. 75APCh. 24.SE - Prob. 76APCh. 24.SE - Propose a structure for the product with formula...Ch. 24.SE - Prob. 78APCh. 24.SE - Prob. 79APCh. 24.SE - Prob. 80APCh. 24.SE - Prob. 81APCh. 24.SE - Prob. 82APCh. 24.SE - Prob. 83APCh. 24.SE - Prob. 84AP
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- Arrange the following amines in order of increasing basicity. For example, an answer of 1234 would indicate that you think 1 is least basic and 4 is most basicarrow_forwardWhen cyclohexanone was reacted with an amine A. It the reaction formed an enamine, whichof the following is the most likely identity of amine A?arrow_forwardWhich of the following amines is more basic? Explain why. NH2 NH2 A Вarrow_forward
- Which of the following is a tertiary amine? C) N-H CH₂ N-CH₂ H₂C b) NH₂ CH₂ CH₂ H₂CH N CH, d) H₂c-c CH, C-CH₂ CHarrow_forwardWhat are the reactions between propanamide and NaOH, H2O; then H3O+?arrow_forwardWhat steps would be used to synthesize an organic amine? Group of answer choices Ketone + oxidizing agent →carboxylic acid + ammonia →organic amine Alkene + acid → alcohol + ammonia →organic amine Ether + acid →ester + ammonia →organic amine Alkane + acid → alcohol + ammonia →organic amine Carboxylic acid + alcohol →ester + ammonia →organic amine Aldehyde + oxidizing agent →carboxylic acid + ammonia → organic aminearrow_forward
- Predict the major products formed when the following amines undergo exhaustivemethylation, treatment with Ag2O, and heating.2-methylpiperidinearrow_forwardPredict the major products formed when the following amines undergo exhaustivemethylation, treatment with Ag2O, and heating.N-ethylpiperidinearrow_forward454 | Chapter 15 Amines (a) Which of the two nitrogen atoms in epibatadine is 54 the stronger base? (b) Mark the three stereocenters in this molecule. Cl H N Narrow_forward
- Kindly answer this questionarrow_forwardWhich of the following best describes the reaction below. 0 H3O+, heat + NH3 CH3* H3C NHCH3 H3C OH The reaction is incorrect, the amine should form along withe the carboxylate because an acid was used. The reaction is incorrect, adding acids to amides forms ketones and amines, not carboxylic acids. The reaction is incorrect, acids can not break amines into carboxylic acids and amides. The reaction is correct, the protonated amine forms because an acid is used to break the amide.arrow_forwardUsing the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forward
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