a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Question

Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…

Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…

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1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Answer 5

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 6

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 7

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 8

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Answer 9

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Answer 10

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 11

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 12

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Answer 13

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Answer 23

Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Solution Summary: The author explains how a retrosynthetic strategy looks at the target molecule and works backwards to arrive at starting materials.

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Chapter 24 Solutions

a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Solution Summary: The author explains how a retrosynthetic strategy looks at the target molecule and works backwards to arrive at starting materials.

a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

b) Interpretation: To describe how the amines to be prepared using reductive amination reactions

c) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Chapter 24 Solutions

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.