a) Br 2 (1 equivalent) Interpretation: To draw the structure of the organic products from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Question

(a) Write the structures of main products when aniline reacts with the following reagents :(i) Br2 water (ii) HCI (iii) (CH3CO)2O/pyridine(b) Arrange the following in the increasing order of their boiling point :C2H5NH2, C2H5OH, (CH3)3N(c) Give a simple chemical test to distinguish between the following pair of compounds : (CH3)2NH and (CH3)3N

Answer 1

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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(a) Write the structures of main products when aniline reacts with the following reagents :(i) Br2 water (ii) HCI (iii) (CH3CO)2O/pyridine(b) Arrange the following in the increasing order of their boiling point :C2H5NH2, C2H5OH, (CH3)3N(c) Give a simple chemical test to distinguish between the following pair of compounds : (CH3)2NH and (CH3)3N

(a) Write the chemical reaction involved in Wolff-Kishner reduction.(b) Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:C6H5COCH3, CH3— CHO, CH3COCH3(c) Why carboxylic acid does not give reactions of carbonyl group?

1. (a) Oxidation of 1-butanol with PCC will produce which of the following? 2-chlorobutanal butanone butanoic acid butanal (b) Which synthetic route is the best way to prepare ethyl isopropyl ether? CH3CH2OH + (CH3)2CHOH + H2SO4, 140 oC CH3CH2ONa + (CH3)2CHOH CH3CH2ONa + (CH3)2CHBr (CH3)2CHONa + CH3CH2Br (c) The Williamson ether synthesis involves nucleophilic substitution involving an alkyl halide and an alcohol. (True or False)

Answer 2

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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Answer 3

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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Answer 4

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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Answer 5

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 6

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 7

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 8

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 9

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 10

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 11

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 12

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Answer 23

Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

a) Br 2 (1 equivalent) Interpretation: To draw the structure of the organic products from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Solution Summary: The author explains the structure of the compound from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Concept explainers

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Chapter 24 Solutions

a) Br 2 (1 equivalent) Interpretation: To draw the structure of the organic products from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Solution Summary: The author explains the structure of the compound from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Concept explainers