The oxidation number of the metal in the given compound has to be determined. Concept introduction: Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions. Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond. Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Question

Assign a systematic name to each of the following chemical compounds:(a) NH4[Cr(NH3)2(NCS)4](b) [Tc(CO)5]I(c) K[Mn(CN)5](d) [Co(NH3)4(OH2)Cl]Br2

Answer 1

Question

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Assign a systematic name to each of the following chemical compounds:(a) NH4[Cr(NH3)2(NCS)4](b) [Tc(CO)5]I(c) K[Mn(CN)5](d) [Co(NH3)4(OH2)Cl]Br2

Name each of the compounds or ions given, including the oxidation state of the metal. (a) [Co(CO3)3]3− (note that CO32− is bidentate in this complex)(b) [Cu(NH3)4]2+(c) [Co(NH3)4Br2]2(SO4)3(d) [Pt(NH3)4][PtCl4](e) [Cr(en)3](NO3)3(f) [Pd(NH3)2Br2] (square planar)(g) K3[Cu(Cl)5](h) [Zn(NH3)2Cl2]

For any of the following that can exist as isomers, state thetype of isomerism and draw the structures: (a) [Co(NH3)5Cl]Br2 (b) [Pt(CH3NH2)3Cl]Br (c) [Fe(H2O)4(NH3)2]2+

Answer 2

Question

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Answer 3

Question

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Answer 4

Question

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Answer 5

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 6

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 7

Chapter 22, Problem 9PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 8

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 9

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 10

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 11

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 12

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 13

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 14

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Answer 25

Ch. 22.1 - Prob. 1RC Ch. 22.2 - Prob. 1Q Ch. 22.2 - 2. Describe the unit cell of austenite. Ch. 22.2 - Prob. 3Q Ch. 22.2 - Prob. 1RC Ch. 22.2 - Prob. 2RC Ch. 22.3 - (a) What is the formula of a complex ion composed...Ch. 22.3 - (a) Determine the metals oxidation number and...Ch. 22.3 - Name the following coordination compounds. (a)...Ch. 22.3 - Prob. 1RC

Solution Summary: The author explains that the oxidation number of the metal in the given compound has to be determined.

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Chapter 22 Solutions