Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 22, Problem 36GQ
Interpretation Introduction
Interpretation: The amount of
Concept introduction: The
Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.
- Structural isomers: Have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).
- Stereoisomers: differ in their spatial arrangement of atoms.
Balanced chemical equation: The
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Chapter 22 Solutions
Chemistry & Chemical Reactivity
Ch. 22.1 - Prob. 1RCCh. 22.2 - Prob. 1QCh. 22.2 - 2. Describe the unit cell of austenite.
Ch. 22.2 - Prob. 3QCh. 22.2 - Prob. 1RCCh. 22.2 - Prob. 2RCCh. 22.3 - (a) What is the formula of a complex ion composed...Ch. 22.3 - (a) Determine the metals oxidation number and...Ch. 22.3 - Name the following coordination compounds. (a)...Ch. 22.3 - Prob. 1RC
Ch. 22.3 - 2. What is the oxidation number of the metal in...Ch. 22.3 - Prob. 3RCCh. 22.3 - Prob. 4RCCh. 22.4 - What types of isomers are possible for the...Ch. 22.4 - Prob. 1RCCh. 22.4 - Prob. 2RCCh. 22.4 - Prob. 3RCCh. 22.4 - Prob. 4RCCh. 22.4 - Prob. 1QCh. 22.5 - Prob. 1CYUCh. 22.5 - Prob. 1RCCh. 22.5 - Prob. 2RCCh. 22.6 - Prob. 1QCh. 22.6 - Prob. 2QCh. 22.6 - Prob. 3QCh. 22.6 - Prob. 4QCh. 22.6 - Prob. 1CYUCh. 22.6 - Prob. 1RCCh. 22.6 - How are the d electrons of Pt distributed in a...Ch. 22.6 - What are the electron configurations for Nd and...Ch. 22.6 - Prob. 3CSCh. 22.6 - Prob. 4CSCh. 22.6 - Prob. 5CSCh. 22 - Prob. 1PSCh. 22 - Prob. 2PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - Prob. 5PSCh. 22 - Prob. 6PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Prob. 11PSCh. 22 - Prob. 12PSCh. 22 - Prob. 13PSCh. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 18PSCh. 22 - Prob. 19PSCh. 22 - Prob. 20PSCh. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33GQCh. 22 - Prob. 34GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 36GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 38GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 41GQCh. 22 - Prob. 42GQCh. 22 - Prob. 43GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 45GQCh. 22 - Prob. 46GQCh. 22 - Prob. 47GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 49GQCh. 22 - Prob. 50GQCh. 22 - Prob. 51GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 57GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 59GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 64GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 71SCQCh. 22 - Prob. 69SCQCh. 22 - Prob. 70SCQ
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- [Fe(H2O)6]3+ (aq) + SCN1- ↔ Fe(H2O)5SCN]2+(aq) + heat yellow red For the above reaction, describe using Le Chatelier’s Principle what changes (color changes and shifts) would occur when each stress is applied to this equilibrium. Explain your answers. a) Add KSCN(aq) b) Decrease temperature c) Add AgNO3, which causes AgSCN to precipitate out.arrow_forwardIn the presence of aqueous ammonia, cobalt(III) forms the complex ion Co(NH3)63+. Determine the molar concentration of free cobalt(III) ion in solution when 0.210 mole of Co(NO3)3 is dissolved in a liter of 2.50 M aqueous ammonia.arrow_forwardCobalt(II) complex ion solution: [Co(H2O)6]+2(aq) + 4Cl-(aq) [CoCl4]-2(aq) + 6H2O(l) Pink Blue 1). When silver nitrate is added the blue color becomes pink. Why is that ? 2. When heat is added , in which direction the equilibrium will shift ? Is this reaction exothermic or endothermic ? 3.What happens when the temperature is lowered in the ice bath ?arrow_forward
- For [Co(NH3)6]3+ , Kf has a value of 5.00 × 1031. Calculate the concentration of free, uncomplexed Co3+ ions in a solution that contains a total of 0.160 mol/L cobalt III ions and an equilibrium concentration of 0.50 M NH3.arrow_forward(a) Draw a Lewis dot and cross structure (including any lone pairs) for a NBr3 molecule and determine the shape of the molecule and number of valence electrons. (b) Six ammonia ligands form a complex ion with Co²+. What is the overall charge of the complex ion? Write the formula for the complex ion. What is the coordination number of the complex ion? Explain how ammonia ligands form a complex ion with Co²+? What is the geometry of the complex ion? Would you expect the complex to be coloured? Explain why? i. ii. iii. iv. V. vi.arrow_forwardHow many geometric isomers exist for [CoCl2(en)2]Cl? How could you determine if your product contains a single geometric isomer or a mixture of geometric isomers?arrow_forward
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- The formation of a complex between cobalt (III) cation and six ammonia (NH3) ligands is very favorable (K₁ = 2.3 x 10³3). Given an initial cobalt concentration of 0.0235 M and an initial ammonia concentration of 0.206 M, what will be the concentration of free cobalt ion (Co³+) at equilibrium? 1.4 x 10-28 M 4.3 x 10-34 M 3.3 x 10-41 M 1.2 x 10-27 M 1.6 x 10-34 Marrow_forwardWhy is [Fe(OH2)6]3+ prepared in an acidic solution? A. It is a Bronsted acid in aqueous solution B. It is stabilized against reduction in acid C. It is not soluble in water at pH = 7.0 D. All of the choicesarrow_forwarddraw the structure of [Fe(NH3)3(OH2)3][PtCl4]arrow_forward
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