Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 22, Problem 51GQ
Interpretation Introduction
Interpretation: The structure of three isomers has to be drawn and chirality has to be predicted.
Concept introduction:
Formula of coordination compounds: Formula of a coordination complex is able to predict by using the metal ion and ligands, and to derive the oxidation number of the coordinated metal ion.
Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.
- Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).
- Stereoisomers: differ in their spatial arrangement of atoms.
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Chapter 22 Solutions
Chemistry & Chemical Reactivity
Ch. 22.1 - Prob. 1RCCh. 22.2 - Prob. 1QCh. 22.2 - 2. Describe the unit cell of austenite.
Ch. 22.2 - Prob. 3QCh. 22.2 - Prob. 1RCCh. 22.2 - Prob. 2RCCh. 22.3 - (a) What is the formula of a complex ion composed...Ch. 22.3 - (a) Determine the metals oxidation number and...Ch. 22.3 - Name the following coordination compounds. (a)...Ch. 22.3 - Prob. 1RC
Ch. 22.3 - 2. What is the oxidation number of the metal in...Ch. 22.3 - Prob. 3RCCh. 22.3 - Prob. 4RCCh. 22.4 - What types of isomers are possible for the...Ch. 22.4 - Prob. 1RCCh. 22.4 - Prob. 2RCCh. 22.4 - Prob. 3RCCh. 22.4 - Prob. 4RCCh. 22.4 - Prob. 1QCh. 22.5 - Prob. 1CYUCh. 22.5 - Prob. 1RCCh. 22.5 - Prob. 2RCCh. 22.6 - Prob. 1QCh. 22.6 - Prob. 2QCh. 22.6 - Prob. 3QCh. 22.6 - Prob. 4QCh. 22.6 - Prob. 1CYUCh. 22.6 - Prob. 1RCCh. 22.6 - How are the d electrons of Pt distributed in a...Ch. 22.6 - What are the electron configurations for Nd and...Ch. 22.6 - Prob. 3CSCh. 22.6 - Prob. 4CSCh. 22.6 - Prob. 5CSCh. 22 - Prob. 1PSCh. 22 - Prob. 2PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - Prob. 5PSCh. 22 - Prob. 6PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Prob. 11PSCh. 22 - Prob. 12PSCh. 22 - Prob. 13PSCh. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 18PSCh. 22 - Prob. 19PSCh. 22 - Prob. 20PSCh. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33GQCh. 22 - Prob. 34GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 36GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 38GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 41GQCh. 22 - Prob. 42GQCh. 22 - Prob. 43GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 45GQCh. 22 - Prob. 46GQCh. 22 - Prob. 47GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 49GQCh. 22 - Prob. 50GQCh. 22 - Prob. 51GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 57GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 59GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 64GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 71SCQCh. 22 - Prob. 69SCQCh. 22 - Prob. 70SCQ
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- [CoF6]3- absorbs 700 nm (red) radiation whereas [Co(H2O)6]3+ absorbs 600 nm (orange) radiation. Please draw the crystal field splitting of the above two complexes. Clearly label the orbitals and show the electron occupation.arrow_forwardAre [Co(NH3)4Cl2]Cl and [Co(NH3)4Cl]Cl2 isomers of each other? If so, what type of isomers are they?arrow_forward8. How many geometrical and/or optical isomers do the following molecules have? Draw a sketch of each isomer and indicate the shape in addition to the types of isomers. a) Pt(NH3)2Br2 b) [Co(phen)2Cl₂]+arrow_forward
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