Explanation Reason for correct option In option (b) pentaamminehydroxochromium ( I I I ) c h l o r i d e , chromium metal makes bond with five ammonia molecule and one O H − molecule. Therefore, the coordination number for the metal in pentaamminehydroxochromium ( I I I ) c h l o r i d e is 6 . Hence the correct option for the metal with coordination 4 is option b. Reasons for incorrect options: In option (a) lithium tetrachlorocobaltate ( I I ) , cobalt metal makes bond with four chloride molecule. Therefore, the coordination number for the metal in lithium tetrachlorocobaltate ( I I ) is 4

9th Edition

ISBN: 9781133949640

Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher: Cengage Learning

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Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

Chapter 22.3, Problem 4RC

Interpretation Introduction

Interpretation: The metal with coordination 4 is to be determined from the given option.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Expert Solution & Answer

Chapter 22 Solutions

Chemistry & Chemical Reactivity

Ch. 22.1 - Prob. 1RC Ch. 22.2 - Prob. 1Q Ch. 22.2 - 2. Describe the unit cell of austenite. Ch. 22.2 - Prob. 3Q Ch. 22.2 - Prob. 1RC Ch. 22.2 - Prob. 2RC Ch. 22.3 - (a) What is the formula of a complex ion composed...Ch. 22.3 - (a) Determine the metals oxidation number and...Ch. 22.3 - Name the following coordination compounds. (a)...Ch. 22.3 - Prob. 1RC

Ch. 22.3 - 2. What is the oxidation number of the metal in...Ch. 22.3 - Prob. 3RC Ch. 22.3 - Prob. 4RC Ch. 22.4 - What types of isomers are possible for the...Ch. 22.4 - Prob. 1RC Ch. 22.4 - Prob. 2RC Ch. 22.4 - Prob. 3RC Ch. 22.4 - Prob. 4RC Ch. 22.4 - Prob. 1Q Ch. 22.5 - Prob. 1CYU Ch. 22.5 - Prob. 1RC Ch. 22.5 - Prob. 2RC Ch. 22.6 - Prob. 1Q Ch. 22.6 - Prob. 2Q Ch. 22.6 - Prob. 3Q Ch. 22.6 - Prob. 4Q Ch. 22.6 - Prob. 1CYU Ch. 22.6 - Prob. 1RC Ch. 22.6 - How are the d electrons of Pt distributed in a...Ch. 22.6 - What are the electron configurations for Nd and...Ch. 22.6 - Prob. 3CS Ch. 22.6 - Prob. 4CS Ch. 22.6 - Prob. 5CS Ch. 22 - Prob. 1PS Ch. 22 - Prob. 2PS Ch. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - Prob. 5PS Ch. 22 - Prob. 6PS Ch. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 9PS Ch. 22 - Prob. 10PS Ch. 22 - Prob. 11PS Ch. 22 - Prob. 12PS Ch. 22 - Prob. 13PS Ch. 22 - Prob. 14PS Ch. 22 - Prob. 15PS Ch. 22 - Prob. 16PS Ch. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 18PS Ch. 22 - Prob. 19PS Ch. 22 - Prob. 20PS Ch. 22 - Prob. 21PS Ch. 22 - Prob. 22PS Ch. 22 - Prob. 23PS Ch. 22 - Prob. 24PS Ch. 22 - Prob. 25PS Ch. 22 - Prob. 26PS Ch. 22 - Prob. 27PS Ch. 22 - Prob. 28PS Ch. 22 - Prob. 29PS Ch. 22 - Prob. 30PS Ch. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 32PS Ch. 22 - Prob. 33GQ Ch. 22 - Prob. 34GQ Ch. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 36GQ Ch. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 38GQ Ch. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 41GQ Ch. 22 - Prob. 42GQ Ch. 22 - Prob. 43GQ Ch. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 45GQ Ch. 22 - Prob. 46GQ Ch. 22 - Prob. 47GQ Ch. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 49GQ Ch. 22 - Prob. 50GQ Ch. 22 - Prob. 51GQ Ch. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 57GQ Ch. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 59GQ Ch. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 64GQ Ch. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 71SCQ Ch. 22 - Prob. 69SCQ Ch. 22 - Prob. 70SCQ

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What is the coordination number of the central metal atom in the following complexes? (a) [Fe(H2O)63+] (b) [Pt(NH3)Br3] (c) [V(en)Cl42] (d) [Au(CN)2+]
Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ions
The glycinate ion, H2NCH2CO2, formed by deprotonation of the amino acid glycine, can function as a bidentate ligand, coordinating to a metal through the nitrogen of the amino group and one of the oxygen atoms. Glycinate ion, a bidentate ligand A copper complex of this ligand has the formula Cu(H2NCH2CO2)2(H2O)2. For this complex, determine the following: (a) the oxidation state of copper (b) the coordination number of copper (c) the number of unpaired electrons (d) whether the complex is diamagnetic or paramagnetic

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