For the given reactions, the possible monochlorination products are to be drawn. Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane ( alkyl halide ) as a final product. To determine: The structure of the possible monochlorination product.

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Answer 1

Question

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

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It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]

Answer 2

Question

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Expert Solution & Answer

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Answer 3

Question

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Expert Solution & Answer

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Answer 4

Question

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

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Answer 5

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 6

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 7

Chapter 22, Problem 122AE

(a)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 8

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 9

(b)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 10

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 11

(c)

Interpretation Introduction

Interpretation: For the given reactions, the possible monochlorination products are to be drawn.

Concept introduction: Alkanes shows a substitution reaction with halogens like chlorine and bromine in the presence of light. The reaction is known as substitution reaction because one of the hydrogen atoms of an alkane is replaced by a halogen atom. The reactions of halogens with alkane yield haloalkane (alkyl halide) as a final product.

To determine: The structure of the possible monochlorination product.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQ Ch. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQ Ch. 22 - Prob. 8RQ Ch. 22 - Prob. 9RQ Ch. 22 - Prob. 10RQ

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Chapter 22 Solutions