Chapter 22, Problem 68E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as $\text{HCl,HBr,and}{\text{H}}_{\text{2}}\text{O}$ add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and $\text{Cl,Br}\text{or}\text{OH}$ forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as $\text{HCl,HBr,and}{\text{H}}_{\text{2}}\text{O}$ add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and $\text{Cl,Br}\text{or}\text{OH}$ forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as $\text{HCl,HBr,and}{\text{H}}_{\text{2}}\text{O}$ add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and $\text{Cl,Br}\text{or}\text{OH}$ forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as $\text{HCl,HBr,and}{\text{H}}_{\text{2}}\text{O}$ add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and $\text{Cl,Br}\text{or}\text{OH}$ forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as $\text{HCl,HBr,and}{\text{H}}_{\text{2}}\text{O}$ add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and $\text{Cl,Br}\text{or}\text{OH}$ forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.