The structure of the monomer from which the given polymer is made is to be determined. Concept Introduction: Polymers are materials made of long repeating chain of molecules called monomer units. Based on the modes of polymerization , polymers are classified as follows: Addition polymers – Addition polymers are formed by repeated addition of the monomer units. The monomer units are unsaturated hydrocarbons generally. There is no elimination of molecules in the reaction. Condensation polymers – Condensation polymers are formed by repeated condensation between two different monomer units along with the formation of elimination products like water.

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 84E

Interpretation Introduction

Interpretation:

The structure of the monomer from which the given polymer is made is to be determined.

Concept Introduction:

Polymers are materials made of long repeating chain of molecules called monomer units. Based on the modes of polymerization, polymers are classified as follows:

Addition polymers – Addition polymers are formed by repeated addition of the monomer units. The monomer units are unsaturated hydrocarbons generally. There is no elimination of molecules in the reaction.

Condensation polymers – Condensation polymers are formed by repeated condensation between two different monomer units along with the formation of elimination products like water.

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.

Answer 2

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 84E

Interpretation Introduction

Interpretation:

The structure of the monomer from which the given polymer is made is to be determined.

Concept Introduction:

Polymers are materials made of long repeating chain of molecules called monomer units. Based on the modes of polymerization, polymers are classified as follows:

Addition polymers – Addition polymers are formed by repeated addition of the monomer units. The monomer units are unsaturated hydrocarbons generally. There is no elimination of molecules in the reaction.

Condensation polymers – Condensation polymers are formed by repeated condensation between two different monomer units along with the formation of elimination products like water.

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Answer 3

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 84E

Interpretation Introduction

Interpretation:

The structure of the monomer from which the given polymer is made is to be determined.

Concept Introduction:

Polymers are materials made of long repeating chain of molecules called monomer units. Based on the modes of polymerization, polymers are classified as follows:

Addition polymers – Addition polymers are formed by repeated addition of the monomer units. The monomer units are unsaturated hydrocarbons generally. There is no elimination of molecules in the reaction.

Condensation polymers – Condensation polymers are formed by repeated condensation between two different monomer units along with the formation of elimination products like water.

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 84E

Interpretation Introduction